Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers

Akio Mishima; Tomomi Koshiyama; Jose A. Real; Masaaki Ohba

doi:10.1039/C7TC00751E

Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers

Akio Mishima, Tomomi Koshiyama, Jose A. Real, Masaaki Ohba

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Mesocrystals of a porous coordination polymer {Fe(pz)[Pt(CN)₄]} (1) showing spin transition were prepared by the reverse micelle method, and the size-controlled mesocrystal 1 kept its porous property and magnetic bistability and exhibited higher guest-responsivity with switching the spin state in both solid and aqueous suspension states than the bulk 1.

Original language	English
Pages (from-to)	3706-3713
Number of pages	8
Journal	Journal of Materials Chemistry C
Volume	5
Issue number	15
DOIs	https://doi.org/10.1039/C7TC00751E
Publication status	Published - 2017

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Chemistry

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title = "Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers",

abstract = "Mesocrystals of a porous coordination polymer {Fe(pz)[Pt(CN)4]} (1) showing spin transition were prepared by the reverse micelle method, and the size-controlled mesocrystal 1 kept its porous property and magnetic bistability and exhibited higher guest-responsivity with switching the spin state in both solid and aqueous suspension states than the bulk 1.",

author = "Akio Mishima and Tomomi Koshiyama and Real, {Jose A.} and Masaaki Ohba",

note = "Funding Information: This study was supported by JSPS KAKENHI Grant Number JP16H06519 (Coordination Asymmetry) and JP15H03787. A. M. thanks JSPS Research Fellow (No. 15J08625). J. A. R. thanks the Spanish Ministerio de Econom{\'i}a y Competitividad (CTQ2016-78341-P and MDM-2015-0538) and Generalitat Valenciana (PROMETEO/2016/147). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/C7TC00751E",

language = "English",

volume = "5",

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journal = "Journal of Materials Chemistry C",

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publisher = "Royal Society of Chemistry",

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T1 - Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers

AU - Mishima, Akio

AU - Koshiyama, Tomomi

AU - Real, Jose A.

AU - Ohba, Masaaki

N1 - Funding Information: This study was supported by JSPS KAKENHI Grant Number JP16H06519 (Coordination Asymmetry) and JP15H03787. A. M. thanks JSPS Research Fellow (No. 15J08625). J. A. R. thanks the Spanish Ministerio de Economía y Competitividad (CTQ2016-78341-P and MDM-2015-0538) and Generalitat Valenciana (PROMETEO/2016/147). Publisher Copyright: © The Royal Society of Chemistry.

PY - 2017

Y1 - 2017

N2 - Mesocrystals of a porous coordination polymer {Fe(pz)[Pt(CN)4]} (1) showing spin transition were prepared by the reverse micelle method, and the size-controlled mesocrystal 1 kept its porous property and magnetic bistability and exhibited higher guest-responsivity with switching the spin state in both solid and aqueous suspension states than the bulk 1.

AB - Mesocrystals of a porous coordination polymer {Fe(pz)[Pt(CN)4]} (1) showing spin transition were prepared by the reverse micelle method, and the size-controlled mesocrystal 1 kept its porous property and magnetic bistability and exhibited higher guest-responsivity with switching the spin state in both solid and aqueous suspension states than the bulk 1.

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DO - 10.1039/C7TC00751E

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JO - Journal of Materials Chemistry C

JF - Journal of Materials Chemistry C

IS - 15

ER -

Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers

Abstract

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