Enhancement of thermoelectric efficiency in type-VIII clathrate Ba 8Ga16Sn30 by Al substitution for Ga

Shukang Deng, Yuta Saiga, Koichiro Suekuni, Toshiro Takabatake

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

Single-crystalline samples of type-VIII clathrate Ba8Ga 16-xAlxSn30 (0≤x≤12) were grown from Sn flux to characterize the structural and thermoelectric properties from 300 to 600 K. The lattice parameter increases by 0.5% as x is increased to 10.5 whose value is the solubility limit of Al. The Seebeck coefficients of all samples are largely negative and the absolute values increase to approximately 300 μV/K on heating to 600 K. This large thermopower coexists with the metallic behavior in the electrical resistivity. The values of resistivity for 1≤x≤6 at 300 K are in the range 3.3-3.8 mωcm which is 70% of that for x=0. As a result, the power factor for x=4 and 6 has a rather large maximum of 1.83× 10-3 W/m K2 at 480 K. The thermal conductivity stays at a low level of 0.72 W/mK up to 480 K, and the sample with x=6 reaches a ZT value of 1.2 at 500 K.

Original languageEnglish
Article number073705
JournalJournal of Applied Physics
Volume108
Issue number7
DOIs
Publication statusPublished - Oct 1 2010

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clathrates
substitutes
augmentation
electrical resistivity
Seebeck effect
guy wires
lattice parameters
thermal conductivity
solubility
heating

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)

Cite this

Enhancement of thermoelectric efficiency in type-VIII clathrate Ba 8Ga16Sn30 by Al substitution for Ga. / Deng, Shukang; Saiga, Yuta; Suekuni, Koichiro; Takabatake, Toshiro.

In: Journal of Applied Physics, Vol. 108, No. 7, 073705, 01.10.2010.

Research output: Contribution to journalArticle

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AB - Single-crystalline samples of type-VIII clathrate Ba8Ga 16-xAlxSn30 (0≤x≤12) were grown from Sn flux to characterize the structural and thermoelectric properties from 300 to 600 K. The lattice parameter increases by 0.5% as x is increased to 10.5 whose value is the solubility limit of Al. The Seebeck coefficients of all samples are largely negative and the absolute values increase to approximately 300 μV/K on heating to 600 K. This large thermopower coexists with the metallic behavior in the electrical resistivity. The values of resistivity for 1≤x≤6 at 300 K are in the range 3.3-3.8 mωcm which is 70% of that for x=0. As a result, the power factor for x=4 and 6 has a rather large maximum of 1.83× 10-3 W/m K2 at 480 K. The thermal conductivity stays at a low level of 0.72 W/mK up to 480 K, and the sample with x=6 reaches a ZT value of 1.2 at 500 K.

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