Enhancing reaction selectivity by intentional control of concentration profile in catalytic microreactor

Shinji Kudo, Taisuke Maki, Hiroyuki Kono, Maria Olea, Kazuhiro Mae

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

This paper reports the results of a computational fluid dynamics (CFD) simulation for a sequential heterogeneous catalytic reaction by comparing the reaction selectivity in a catalytic microreactor with that in a conventional catalytic packed-bed reactor. The comparative simulation revealed that the catalytic microreactor has an advantage over the conventional reactor in the diffusion control regime, and that the control of concentration distribution of reactants by molecular diffusion in the microspace can enhance the selectivity of the desired product. The concentration distribution was intentionally controlled by the shape of the microreactor. The yield of the desired product in the microreactor was 1.16 times that in the packed-bed reactor. CFD simulation of methanol decomposition was also performed by fitting the parameters with the experimental results. The results of the CFD simulation verified the advantage of the microreactor.

Original languageEnglish
Pages (from-to)63-69
Number of pages7
JournalJournal of Chemical Engineering of Japan
Volume43
Issue number1 SUPPL.
DOIs
Publication statusPublished - Feb 5 2010
Externally publishedYes

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Computational fluid dynamics
Packed beds
Computer simulation
Methanol
Decomposition

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Enhancing reaction selectivity by intentional control of concentration profile in catalytic microreactor. / Kudo, Shinji; Maki, Taisuke; Kono, Hiroyuki; Olea, Maria; Mae, Kazuhiro.

In: Journal of Chemical Engineering of Japan, Vol. 43, No. 1 SUPPL., 05.02.2010, p. 63-69.

Research output: Contribution to journalArticle

Kudo, Shinji ; Maki, Taisuke ; Kono, Hiroyuki ; Olea, Maria ; Mae, Kazuhiro. / Enhancing reaction selectivity by intentional control of concentration profile in catalytic microreactor. In: Journal of Chemical Engineering of Japan. 2010 ; Vol. 43, No. 1 SUPPL. pp. 63-69.
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