TY - JOUR
T1 - Erratum
T2 - Synthetic β-1,2-mannosyloxymannitol glycolipid from the fungus malassezia pachydermatis signals through human mincle (Journal of Organic Chemistry (2019) 84:11 (6788-6797) DOI: 10.1021/acs.joc.9b00544)
AU - Van Der Peet, Phillip L.
AU - Gunawan, Christian
AU - Watanabe, Miyuki
AU - Yamasaki, Sho
AU - Williams, Spencer J.
N1 - Publisher Copyright:
© 2019 American Chemical Society.
PY - 2019/7/19
Y1 - 2019/7/19
N2 - Several errors have been inadvertently made in the representation of the stereochemistry of the 10-oxystearic acid residue in compounds 17, 18, 19, and 44-2, and in the naming of compounds 3, 4, 8, 10, 11, 12, 13, 14, 15, 17, 18, 19, and 44-2. In all cases the stereochemistry is 10-(R). The corrected names are M e t h y l ( R ) - 1 0 - ( 2 , 3 , 4 , 6 - t e t r a -O- b e n z y l - ß - D - mannopyranosyloxy)stearate (3) Methyl (R)-10-(2-O-(2,3,4,6-tetra-O-benzyl-ß-D-mannopyranosyl)- 3,4,6-tri-O-benzyl-ß-D-mannopyranosyloxy)stearate (4) Methyl (R)-10-(2-O-acetyl-3,4,6-tri-O-benzyl-ß-Dglucopyranosyloxy) stearate (8) Methyl (R)-10-(3,4,6-tri-O-benzyl-ß-D-glucopyranosyloxy)- stearate (9) M e t h y l ( R ) - 1 0 - ( 3 , 4 , 6 - t r i - O - b e n z y l - ß - D - mannopyranosyloxy)stearate (10) (R)-10-(2,3,4,6-tetra-O-benzyl-ß-D-mannopyranosyloxy)- stearic acid (11) Methyl (R)-10-(2-O-(2-O-acetyl-3,4,6-tri-O-benzyl-ß-D-glucopyranosyl)- 3,4,6-tri-O-benzyl-ß-D-mannopyranosyloxy)- stearate (12) Methyl (R)-10-(2-O-(3,4,6-tri-O-benzyl-ß-D-glucopyranosyl)- 3,4,6-tri-O-benzyl-ß-D-mannopyranosyloxy)stearate (13) Methyl (R)-10-(2-O-(3,4,6-tri-O-benzyl-ß-D-mannopyranosyl)- 3,4,6-tri-O-benzyl-ß-D-mannopyranosyloxy)stearate (14) (R)-10-(2-O-(2,3,4,6-tetra-O-benzyl-ß-D-mannopyranosyl)- 3,4,6-tri-O-benzyl-ß-D-mannopyranosyloxy)stearic acid (15) 1,2;5,6-Di-O-isopropylidene-3,4-di-O-((R)-10-(2,3,4,6-tetra- O-benzyl-ß-D-mannopyranosyloxy)stearoyl)-L-mannitol (17) 3 ,4-Di -O- ( (R) - 1 0 - ( 2 , 3 , 4 , 6 - t e t r a -O- b e n z y l - ß- D - mannopyranosyloxy)stearoyl)-L-mannitol (18) 1-O-((R)-10-(2-O-(2,3,4,6-tetra-O-benzyl-ß-D-mannopyranosyl)- 3,4,6-tri-O-benzyl-ß-D-mannopyranosyloxy)stearoyl)- 3 , 4 - d i -O- ( ( R ) - 1 0 - ( 2 , 3 , 4 , 6 - t e t r a -O- b e n z y l - ß - D - mannopyranosyloxy)stearoyl)-L-mannitol (19) -O- ( (R ) - 1 0 - ( 2 -O- ß - D - M a n n o p y r a n o s y l -ß - D - mannopyranosyloxy)stearoyl)-3,4-di-O-((R)-10-ß-D-mannopyranosyloxystearoyl)- L-mannitol, 44-2 The corrected Graphical Abstract, Figure 1, and Scheme 4 are shown below. In addition, these errors have been continued into the Supporting Information. The entire Supporting Information file should be replaced with the corrected version supplied with this correction.
AB - Several errors have been inadvertently made in the representation of the stereochemistry of the 10-oxystearic acid residue in compounds 17, 18, 19, and 44-2, and in the naming of compounds 3, 4, 8, 10, 11, 12, 13, 14, 15, 17, 18, 19, and 44-2. In all cases the stereochemistry is 10-(R). The corrected names are M e t h y l ( R ) - 1 0 - ( 2 , 3 , 4 , 6 - t e t r a -O- b e n z y l - ß - D - mannopyranosyloxy)stearate (3) Methyl (R)-10-(2-O-(2,3,4,6-tetra-O-benzyl-ß-D-mannopyranosyl)- 3,4,6-tri-O-benzyl-ß-D-mannopyranosyloxy)stearate (4) Methyl (R)-10-(2-O-acetyl-3,4,6-tri-O-benzyl-ß-Dglucopyranosyloxy) stearate (8) Methyl (R)-10-(3,4,6-tri-O-benzyl-ß-D-glucopyranosyloxy)- stearate (9) M e t h y l ( R ) - 1 0 - ( 3 , 4 , 6 - t r i - O - b e n z y l - ß - D - mannopyranosyloxy)stearate (10) (R)-10-(2,3,4,6-tetra-O-benzyl-ß-D-mannopyranosyloxy)- stearic acid (11) Methyl (R)-10-(2-O-(2-O-acetyl-3,4,6-tri-O-benzyl-ß-D-glucopyranosyl)- 3,4,6-tri-O-benzyl-ß-D-mannopyranosyloxy)- stearate (12) Methyl (R)-10-(2-O-(3,4,6-tri-O-benzyl-ß-D-glucopyranosyl)- 3,4,6-tri-O-benzyl-ß-D-mannopyranosyloxy)stearate (13) Methyl (R)-10-(2-O-(3,4,6-tri-O-benzyl-ß-D-mannopyranosyl)- 3,4,6-tri-O-benzyl-ß-D-mannopyranosyloxy)stearate (14) (R)-10-(2-O-(2,3,4,6-tetra-O-benzyl-ß-D-mannopyranosyl)- 3,4,6-tri-O-benzyl-ß-D-mannopyranosyloxy)stearic acid (15) 1,2;5,6-Di-O-isopropylidene-3,4-di-O-((R)-10-(2,3,4,6-tetra- O-benzyl-ß-D-mannopyranosyloxy)stearoyl)-L-mannitol (17) 3 ,4-Di -O- ( (R) - 1 0 - ( 2 , 3 , 4 , 6 - t e t r a -O- b e n z y l - ß- D - mannopyranosyloxy)stearoyl)-L-mannitol (18) 1-O-((R)-10-(2-O-(2,3,4,6-tetra-O-benzyl-ß-D-mannopyranosyl)- 3,4,6-tri-O-benzyl-ß-D-mannopyranosyloxy)stearoyl)- 3 , 4 - d i -O- ( ( R ) - 1 0 - ( 2 , 3 , 4 , 6 - t e t r a -O- b e n z y l - ß - D - mannopyranosyloxy)stearoyl)-L-mannitol (19) -O- ( (R ) - 1 0 - ( 2 -O- ß - D - M a n n o p y r a n o s y l -ß - D - mannopyranosyloxy)stearoyl)-3,4-di-O-((R)-10-ß-D-mannopyranosyloxystearoyl)- L-mannitol, 44-2 The corrected Graphical Abstract, Figure 1, and Scheme 4 are shown below. In addition, these errors have been continued into the Supporting Information. The entire Supporting Information file should be replaced with the corrected version supplied with this correction.
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U2 - 10.1021/acs.joc.9b01609
DO - 10.1021/acs.joc.9b01609
M3 - Comment/debate
C2 - 31244087
AN - SCOPUS:85068320050
SN - 0022-3263
VL - 84
SP - 9393
EP - 9394
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
IS - 14
ER -