Establishing the mechanism of Rh-catalysed activation of O 2 by H 2

Daisuke Inoki, Takahiro Matsumoto, Hideki Hayashi, Keisuke Takashita, Hidetaka Nakai, Seiji Ogo

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Reductive activation of O 2 by H 2 with rhodium terpyridine complexes in H 2O and CH 3CN is described and the mechanism is fully elucidated. The rhodium complex extracts electrons from H 2 and reductively activates O 2 to form a peroxo active intermediate. This intermediate is able to oxidise triphenyl phosphine to triphenyl phosphine oxide. A model system constructed in CH 3CN provides isolable analogues of catalytic intermediates in H 2O, allowing a detailed look at each step in the catalytic cycle.

Original languageEnglish
Pages (from-to)4328-4334
Number of pages7
JournalDalton Transactions
Volume41
Issue number15
DOIs
Publication statusPublished - Apr 21 2012

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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