Evidences for Bromo-Bridged One-Dimensional Chain Structure of the Mixed-Valence Gold Complexes with the Empirical Formulas, (AuBr2(DBS)) and (AuBrCl(DBS))(DBS=dibenzyl sulfide).

Kazuhiro Takahashi, Hiroshi Tanino

Research output: Contribution to journalArticlepeer-review

Abstract

The bromo-bridged one-dimensional chain structure of [AuBr<SUB>2</SUB>(DBS)] is revealed by X-ray analysis. The bromo-bridged skeleton of the one-dimensional chain of [AuBrCl(DBS)] is identified by comparing its unit cell parameters, visible absorption spectrum on nujol mull, and Br K near-edge X-ray absorption spectra with those of [AuBr<SUB>2</SUB>(DBS)].
Original languageEnglish
Pages (from-to)1977-1980
Number of pages4
JournalChemistry Letters
Issue number11
DOIs
Publication statusPublished - 1991

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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