TY - JOUR
T1 - Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions
AU - Seo, Mi Sook
AU - Kamachi, Takashi
AU - Kouno, Tomohisa
AU - Murata, Koji
AU - Park, Mi Joo
AU - Yoshizawa, Kazunari
AU - Nam, Wonwoo
PY - 2007/6/29
Y1 - 2007/6/29
N2 - The active oxidant that oxygenates organic substrates is an iron(IV) oxo intermediate, namely, [(tpa)FeIV(O)(CH3CN)]2+ (2), which is formed through O-O bond homolysis, according to experimental and computational studies on the reactivity of nonheme iron(III) alkylperoxo complex [(tpa)FeIII(OOtBu)(CH3CN)]2+ (1), which was shown to be a sluggish electrophilic oxidant that is incapable of oxygenating organic substrates. tpa = tris(2-pyridylmethyl)amine. (Chemical Equation Presented).
AB - The active oxidant that oxygenates organic substrates is an iron(IV) oxo intermediate, namely, [(tpa)FeIV(O)(CH3CN)]2+ (2), which is formed through O-O bond homolysis, according to experimental and computational studies on the reactivity of nonheme iron(III) alkylperoxo complex [(tpa)FeIII(OOtBu)(CH3CN)]2+ (1), which was shown to be a sluggish electrophilic oxidant that is incapable of oxygenating organic substrates. tpa = tris(2-pyridylmethyl)amine. (Chemical Equation Presented).
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U2 - 10.1002/anie.200604219
DO - 10.1002/anie.200604219
M3 - Article
C2 - 17304600
AN - SCOPUS:34250164725
VL - 46
SP - 2291
EP - 2294
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 13
ER -