Abstract
The active oxidant that oxygenates organic substrates is an iron(IV) oxo intermediate, namely, [(tpa)FeIV(O)(CH3CN)]2+ (2), which is formed through O-O bond homolysis, according to experimental and computational studies on the reactivity of nonheme iron(III) alkylperoxo complex [(tpa)FeIII(OOtBu)(CH3CN)]2+ (1), which was shown to be a sluggish electrophilic oxidant that is incapable of oxygenating organic substrates. tpa = tris(2-pyridylmethyl)amine. (Chemical Equation Presented).
Original language | English |
---|---|
Pages (from-to) | 2291-2294 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 46 |
Issue number | 13 |
DOIs | |
Publication status | Published - Jun 29 2007 |
Fingerprint
All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
Cite this
Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions. / Seo, Mi Sook; Kamachi, Takashi; Kouno, Tomohisa; Murata, Koji; Park, Mi Joo; Yoshizawa, Kazunari; Nam, Wonwoo.
In: Angewandte Chemie - International Edition, Vol. 46, No. 13, 29.06.2007, p. 2291-2294.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions
AU - Seo, Mi Sook
AU - Kamachi, Takashi
AU - Kouno, Tomohisa
AU - Murata, Koji
AU - Park, Mi Joo
AU - Yoshizawa, Kazunari
AU - Nam, Wonwoo
PY - 2007/6/29
Y1 - 2007/6/29
N2 - The active oxidant that oxygenates organic substrates is an iron(IV) oxo intermediate, namely, [(tpa)FeIV(O)(CH3CN)]2+ (2), which is formed through O-O bond homolysis, according to experimental and computational studies on the reactivity of nonheme iron(III) alkylperoxo complex [(tpa)FeIII(OOtBu)(CH3CN)]2+ (1), which was shown to be a sluggish electrophilic oxidant that is incapable of oxygenating organic substrates. tpa = tris(2-pyridylmethyl)amine. (Chemical Equation Presented).
AB - The active oxidant that oxygenates organic substrates is an iron(IV) oxo intermediate, namely, [(tpa)FeIV(O)(CH3CN)]2+ (2), which is formed through O-O bond homolysis, according to experimental and computational studies on the reactivity of nonheme iron(III) alkylperoxo complex [(tpa)FeIII(OOtBu)(CH3CN)]2+ (1), which was shown to be a sluggish electrophilic oxidant that is incapable of oxygenating organic substrates. tpa = tris(2-pyridylmethyl)amine. (Chemical Equation Presented).
UR - http://www.scopus.com/inward/record.url?scp=34250164725&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=34250164725&partnerID=8YFLogxK
U2 - 10.1002/anie.200604219
DO - 10.1002/anie.200604219
M3 - Article
C2 - 17304600
AN - SCOPUS:34250164725
VL - 46
SP - 2291
EP - 2294
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 13
ER -