Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions

Mi Sook Seo, Takashi Kamachi, Tomohisa Kouno, Koji Murata, Mi Joo Park, Kazunari Yoshizawa, Wonwoo Nam

Research output: Contribution to journal › Article

50 Citations (Scopus)

Abstract

The active oxidant that oxygenates organic substrates is an iron(IV) oxo intermediate, namely, [(tpa)FeIV(O)(CH3CN)]2+ (2), which is formed through O-O bond homolysis, according to experimental and computational studies on the reactivity of nonheme iron(III) alkylperoxo complex [(tpa)FeIII(OOtBu)(CH3CN)]2+ (1), which was shown to be a sluggish electrophilic oxidant that is incapable of oxygenating organic substrates. tpa = tris(2-pyridylmethyl)amine. (Chemical Equation Presented).

Original languageEnglish
Pages (from-to)2291-2294
Number of pages4
JournalAngewandte Chemie - International Edition
Volume46
Issue number13
DOIs
Publication statusPublished - Jun 29 2007

Fingerprint

Oxygenation
Oxidants
Iron
Substrates
Amines
tris(2-pyridylmethyl)amine
ferryl iron

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions. / Seo, Mi Sook; Kamachi, Takashi; Kouno, Tomohisa; Murata, Koji; Park, Mi Joo; Yoshizawa, Kazunari; Nam, Wonwoo.

In: Angewandte Chemie - International Edition, Vol. 46, No. 13, 29.06.2007, p. 2291-2294.

Research output: Contribution to journal › Article

Seo, MS, Kamachi, T, Kouno, T, Murata, K, Park, MJ, Yoshizawa, K & Nam, W 2007, 'Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions', Angewandte Chemie - International Edition, vol. 46, no. 13, pp. 2291-2294. https://doi.org/10.1002/anie.200604219
Seo MS, Kamachi T, Kouno T, Murata K, Park MJ, Yoshizawa K et al. Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions. Angewandte Chemie - International Edition. 2007 Jun 29;46(13):2291-2294. https://doi.org/10.1002/anie.200604219
Seo, Mi Sook ; Kamachi, Takashi ; Kouno, Tomohisa ; Murata, Koji ; Park, Mi Joo ; Yoshizawa, Kazunari ; Nam, Wonwoo. / Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions. In: Angewandte Chemie - International Edition. 2007 ; Vol. 46, No. 13. pp. 2291-2294.
@article{759bf49729e7431d89e746340c8a9257,
title = "Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions",
abstract = "The active oxidant that oxygenates organic substrates is an iron(IV) oxo intermediate, namely, [(tpa)FeIV(O)(CH3CN)]2+ (2), which is formed through O-O bond homolysis, according to experimental and computational studies on the reactivity of nonheme iron(III) alkylperoxo complex [(tpa)FeIII(OOtBu)(CH3CN)]2+ (1), which was shown to be a sluggish electrophilic oxidant that is incapable of oxygenating organic substrates. tpa = tris(2-pyridylmethyl)amine. (Chemical Equation Presented).",
author = "Seo, {Mi Sook} and Takashi Kamachi and Tomohisa Kouno and Koji Murata and Park, {Mi Joo} and Kazunari Yoshizawa and Wonwoo Nam",
year = "2007",
month = "6",
day = "29",
doi = "10.1002/anie.200604219",
language = "English",
volume = "46",
pages = "2291--2294",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "13",

}

TY - JOUR

T1 - Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions

AU - Seo, Mi Sook

AU - Kamachi, Takashi

AU - Kouno, Tomohisa

AU - Murata, Koji

AU - Park, Mi Joo

AU - Yoshizawa, Kazunari

AU - Nam, Wonwoo

PY - 2007/6/29

Y1 - 2007/6/29

N2 - The active oxidant that oxygenates organic substrates is an iron(IV) oxo intermediate, namely, [(tpa)FeIV(O)(CH3CN)]2+ (2), which is formed through O-O bond homolysis, according to experimental and computational studies on the reactivity of nonheme iron(III) alkylperoxo complex [(tpa)FeIII(OOtBu)(CH3CN)]2+ (1), which was shown to be a sluggish electrophilic oxidant that is incapable of oxygenating organic substrates. tpa = tris(2-pyridylmethyl)amine. (Chemical Equation Presented).

AB - The active oxidant that oxygenates organic substrates is an iron(IV) oxo intermediate, namely, [(tpa)FeIV(O)(CH3CN)]2+ (2), which is formed through O-O bond homolysis, according to experimental and computational studies on the reactivity of nonheme iron(III) alkylperoxo complex [(tpa)FeIII(OOtBu)(CH3CN)]2+ (1), which was shown to be a sluggish electrophilic oxidant that is incapable of oxygenating organic substrates. tpa = tris(2-pyridylmethyl)amine. (Chemical Equation Presented).

UR - http://www.scopus.com/inward/record.url?scp=34250164725&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34250164725&partnerID=8YFLogxK

U2 - 10.1002/anie.200604219

DO - 10.1002/anie.200604219

M3 - Article

C2 - 17304600

AN - SCOPUS:34250164725

VL - 46

SP - 2291

EP - 2294

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 13

ER -

Access to Document