Experimental pattern transitions in a Liesegang system

A. Toramaru, T. Harada, T. Okamura

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

We experimentally found various patterns of precipitation in a lead iodide Liesegang system: periodic precipitation, continuous tree-like crystal aggregates and periodic tree-like crystal aggregates. Gel and reactant concentrations are two major controlling factors. At high gel concentrations, Liesegang band forms, whereas at low gel concentrations, tree-like crystal aggregates similar to diffusion-limited aggregation (DLA) develop in the entire system. At an intermediate gel concentration, Liesegang band and tree-like crystal aggregates coexist. At lower reactant concentration, the periodic tree-like crystal aggregates tends to form. A simple scaling argument that the kinetics of bulk and surface nucleation plays an important role, is presented to understand the effect of gel concentration on pattern transition.

Original languageEnglish
Pages (from-to)133-140
Number of pages8
JournalPhysica D: Nonlinear Phenomena
Volume183
Issue number1-2
DOIs
Publication statusPublished - Sep 1 2003
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Statistical and Nonlinear Physics
  • Mathematical Physics
  • Condensed Matter Physics
  • Applied Mathematics

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