Experimental study on thermal conductivity of free-standing fluorinated single-layer graphene

Masahiro Narasaki, Haidong Wang, Takashi Nishiyama, Tatsuya Ikuta, Koji Takahashi

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

We measured the thermal conductivity of free-standing fluorinated single-layer graphene (FSLG) using a precise T-type method. Pristine graphene was fluorinated and suspended above the substrate using xenon difluoride gas. Compared with the thermal conductivity of pristine single-layer graphene (SLG) (∼2000 W/mK) previously measured by the same T-type method for the same original SLG, the FSLG exhibited a much lower thermal conductivity (∼80 W/mK) and a weak dependence of the thermal conductivity on nanohole defects. The experimental results suggest that the fluorine atoms and sp3 bonding in the FSLG strongly contributed to phonon scattering. The phonon scattering by the fluorine atoms and sp3 bonding has a dominant effect on the thermal conductivity decrease over the phonon scattering by nanohole defects. This study lays a foundation for the thermal measurement of 2D fluorinated materials and benefits future applications of fluorinated graphene.

Original languageEnglish
Article number093103
JournalApplied Physics Letters
Volume111
Issue number9
DOIs
Publication statusPublished - Aug 28 2017

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graphene
thermal conductivity
fluorine
scattering
difluorides
defects
xenon
atoms
gases

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy (miscellaneous)

Cite this

Experimental study on thermal conductivity of free-standing fluorinated single-layer graphene. / Narasaki, Masahiro; Wang, Haidong; Nishiyama, Takashi; Ikuta, Tatsuya; Takahashi, Koji.

In: Applied Physics Letters, Vol. 111, No. 9, 093103, 28.08.2017.

Research output: Contribution to journalArticle

Narasaki, Masahiro ; Wang, Haidong ; Nishiyama, Takashi ; Ikuta, Tatsuya ; Takahashi, Koji. / Experimental study on thermal conductivity of free-standing fluorinated single-layer graphene. In: Applied Physics Letters. 2017 ; Vol. 111, No. 9.
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