External magnetic field effects on photoinduced electron transfer reactions in phenothiazine-viologen-linked systems complexed with cyclodextrins

Hiroaki Yonemura, Hiroshi Nakamura, Taku Matsuo

Research output: Contribution to journalArticle

53 Citations (Scopus)

Abstract

External magnetic field effects on photoinduced electron transfer in phenothiazine-viologen-linked compounds were examined in the presence of cyclodextrins in aqueous solutions. Laser excitation (351 nm) afforded a phenothiazine-viologen radical pair, when the linked compound, with twelve methylene groups as a spacer, was complexed with either α- or β-cyclodextrin. The decay rate of the radical pair was reduced by an order of magnitude on going from 0 to 0.3 T, above which the rate remained constant. The results were explained on the basis of electron spin relaxation in the CDx complexes with extended spacer as suggested by the fluorescence and NMR spectra.

Original languageEnglish
Pages (from-to)157-161
Number of pages5
JournalChemical Physics Letters
Volume155
Issue number2
DOIs
Publication statusPublished - Feb 24 1989

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Viologens
Magnetic field effects
phenothiazines
Cyclodextrins
spacers
electron transfer
Laser excitation
Electrons
magnetic fields
methylene
electron spin
decay rates
Fluorescence
Nuclear magnetic resonance
aqueous solutions
fluorescence
nuclear magnetic resonance
excitation
lasers
phenothiazine

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

External magnetic field effects on photoinduced electron transfer reactions in phenothiazine-viologen-linked systems complexed with cyclodextrins. / Yonemura, Hiroaki; Nakamura, Hiroshi; Matsuo, Taku.

In: Chemical Physics Letters, Vol. 155, No. 2, 24.02.1989, p. 157-161.

Research output: Contribution to journalArticle

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