TY - JOUR
T1 - Extraction of rare-earth ions with an 8-hydroxyquinoline derivative in an ionic liquid
AU - Yang, Fan
AU - Kubota, Fukiko
AU - Kamiya, Noriho
AU - Goto, Masahiro
PY - 2013
Y1 - 2013
N2 - The extraction behavior of rare-earth ions with an 8-hydroxyquinoline derivative, HO8Q (5-octyloxymethyl-8-quinolinol), was studied using an ionic liquid, [C8mim][Tf2N] (1-octyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide), as the extracting phase. Compared with a conventional organic solvent, n-dodecane, the ionic liquid system showed a higher extraction ability for a heavy rare earth, Dy, and a better selectivity between Dy and Nd (separation factor βDy/Nd: 108). In the liquid-liquid extraction system, the color of the extracting phase changed from colorless to light yellow along with the extraction of rare-earth ions. Furthermore, the extraction efficiency was enhanced by the addition of TOPO (tri-n-octylphosphine oxide) as a co-extractant.
AB - The extraction behavior of rare-earth ions with an 8-hydroxyquinoline derivative, HO8Q (5-octyloxymethyl-8-quinolinol), was studied using an ionic liquid, [C8mim][Tf2N] (1-octyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide), as the extracting phase. Compared with a conventional organic solvent, n-dodecane, the ionic liquid system showed a higher extraction ability for a heavy rare earth, Dy, and a better selectivity between Dy and Nd (separation factor βDy/Nd: 108). In the liquid-liquid extraction system, the color of the extracting phase changed from colorless to light yellow along with the extraction of rare-earth ions. Furthermore, the extraction efficiency was enhanced by the addition of TOPO (tri-n-octylphosphine oxide) as a co-extractant.
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U2 - 10.15261/serdj.20.123
DO - 10.15261/serdj.20.123
M3 - Article
AN - SCOPUS:84879213249
SN - 1341-7215
VL - 20
SP - 123
EP - 129
JO - Solvent Extraction Research and Development
JF - Solvent Extraction Research and Development
ER -