Fabrication of β-TCP foam: Effects of magnesium oxide as phase stabilizer on its properties

Taro Nikaido, Kanji Tsuru, Melvin Munar, Michito Maruta, Shigeki Matsuya, Seiji Nakamura, Kunio Ishikawa

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Porous β-tricalcium phosphate (β-TCP) has attracted attention as an artificial bone substitute. α-TCP foam that mimics the fully interconnected porous structure of the cancellous bone can be fabricated by a ceramics foam method, which requires sintering at high temperature. However, β-TCP foam could not be fabricated by the ceramics foam method since the sintering temperature required is above the αβ transition temperature. To fabricate the β-TCP foam that mimics the fully interconnected porous structure of cancellous bone, magnesium oxide (MgO) is added as a phase stabilizer. β-TCP foam was obtained when at least 3 mol% MgO was added. Lattice parameter analysis revealed that the MgO as a β-phase stabilizer was incorporated into the lattice of the TCP structure. The porosity of the β-TCP foam containing 3 mol% MgO was 92%, and the compressive strength was approximately 32 kPa. Despite the observed smooth surface and lower porosity of β-TCP foam compared to α-TCP foam, no improvement on the compressive strength of β-TCP foam occurred even by the addition of 3 mol% or more of MgO. Formation of micro-cracks could be one the reasons. These micro-cracks were formed by contraction as a result from growth of adjacent grains.

Original languageEnglish
Pages (from-to)14245-14250
Number of pages6
JournalCeramics International
Volume41
Issue number10
DOIs
Publication statusPublished - May 7 2015

Fingerprint

Magnesium Oxide
Magnesia
Foams
Fabrication
Ceramic foams
Bone
Compressive strength
Sintering
Porosity
Cracks
Bone Substitutes
Superconducting transition temperature
Lattice constants
Phosphates
Temperature

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Process Chemistry and Technology
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

Fabrication of β-TCP foam : Effects of magnesium oxide as phase stabilizer on its properties. / Nikaido, Taro; Tsuru, Kanji; Munar, Melvin; Maruta, Michito; Matsuya, Shigeki; Nakamura, Seiji; Ishikawa, Kunio.

In: Ceramics International, Vol. 41, No. 10, 07.05.2015, p. 14245-14250.

Research output: Contribution to journalArticle

Nikaido, Taro ; Tsuru, Kanji ; Munar, Melvin ; Maruta, Michito ; Matsuya, Shigeki ; Nakamura, Seiji ; Ishikawa, Kunio. / Fabrication of β-TCP foam : Effects of magnesium oxide as phase stabilizer on its properties. In: Ceramics International. 2015 ; Vol. 41, No. 10. pp. 14245-14250.
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