Fabrication of a photoelectrochemical cell using a self-assembled monolayer of tris(2,2′-bipyrisine)ruthenium(II)-viologen linked thiol on multistructured gold nanoparticles

Nao Terasaki, Keisuke Otsuka, Tsuyoshi Akiyama, Sunao Yamada

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    10 Citations (Scopus)

    Abstract

    A novel photoelectrochemical cell consisting of a modified electrode with a self-assembled monolayer of a tris(2,2′bipyridine)ruthenium(II)-viologen linked thiol on the surfaces of a gold-particle multistructure, an indium-tin-oxide (ITO) electrode, and an aqueous electrolyte solution containing hydroxymethylferrocene, has been fabricated. The modified electrode was constructed by the precipitation of gold nanoparticles on a planar gold electrode, and by subsequent self-assembling of the thiol compound on the surfaces of the multistructure. The spatial separation between the modified electrode and the ITO electrode was as small as ∼12 μm, which was determined from the thickness of a polyimide film used for electrical insulation. The performance of the photoelectrochemical cell was investigated. Photocurrents and photovoltages increased with increasing number of immobilized molecules.

    Original languageEnglish
    Pages (from-to)2372-2375
    Number of pages4
    JournalJapanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers
    Volume43
    Issue number4 B
    DOIs
    Publication statusPublished - Apr 2004

    All Science Journal Classification (ASJC) codes

    • Engineering(all)
    • Physics and Astronomy(all)

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