Fabrication of layered niobium oxysulfide and investigation of structural and elemental composition

Kazuyoshi Izawa, Shintaro Ida, Ugur Unal, Tomoki Yamaguchi, Yasumichi Matsumoto

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    The layered niobium oxysulfide was synthesized by the heat treatment of K4Nb6O17 · 3H2O layered oxide in the mixture of H2SZN2 gases. The layered oxysulfide had the large plate-like shape, and the total ratio of compound was estimated KxNbS2-yOy (The number of x was from 0.2 to 0.4, y was from about 0.5 to 1.0). According to the XPS measurement, the oxidation state of Nb was estimated for +2, +4, +5, and oxidation state of S was -2. It was confirmed that the layered oxysulfide has ion exchange, and intercalation capabilities as proton exchange reactions take place in H 2SO4 solution and bulky amine molecules can be intercalated in an amine solution.

    Original languageEnglish
    Title of host publicationSolid-State Chemistry of Inorganic Materials VI
    PublisherMaterials Research Society
    Pages189-193
    Number of pages5
    ISBN (Print)9781604234336
    DOIs
    Publication statusPublished - 2006
    Event2006 MRS Fall Meeting - Boston, MA, United States
    Duration: Nov 27 2006Dec 1 2006

    Publication series

    NameMaterials Research Society Symposium Proceedings
    Volume988
    ISSN (Print)0272-9172

    Other

    Other2006 MRS Fall Meeting
    CountryUnited States
    CityBoston, MA
    Period11/27/0612/1/06

    All Science Journal Classification (ASJC) codes

    • Materials Science(all)
    • Condensed Matter Physics
    • Mechanics of Materials
    • Mechanical Engineering

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