Facile method for the preparation of tri‐O‐(alkyl)cellulose

Tetsuo Kondo, Derek G. Gray

Research output: Contribution to journalArticle

50 Citations (Scopus)

Abstract

A simple way to prepare tri‐O‐(alkyl)cellulose from cellulose acetate (CA) in dimethylsulfoxide (DMSO) using the appropriate alkyl iodide and NaOH has been developed. In this procedure, the addition of a small amount of water to the DMSO solution improved the efficiency of etherification. The substitution pattern of (methyl)cellulose (MC) was investigated to determine the effect of added water on the relative reactivities of the glucose ring substituents. This etherification method can be applied to alkylate other polymers with acetate‐functional groups that are soluble in DMSO.

Original languageEnglish
Pages (from-to)417-423
Number of pages7
JournalJournal of Applied Polymer Science
Volume45
Issue number3
DOIs
Publication statusPublished - Jan 1 1992
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Polymers and Plastics
  • Materials Chemistry

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