Facile oxidation of aldehydes and α-keto acids as catalyzed by flavin and thiazolium ion

Seiji Shinkai, Takaharu Yamashita, Yumiko Kusano, Osamu Manabe

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Oxidation of aldehydes and α-keto acids to carboxylic acids ocurrs readily in the presence of a flavin, thiazolium ion, and cationic micelles, the reaction involving trapping by the flavin of the intermediate formed from the substrate-thiazolium adducts through deprotonation or decarboxylation.

Original languageEnglish
Pages (from-to)2543-2546
Number of pages4
JournalTetrahedron Letters
Volume21
Issue number26
DOIs
Publication statusPublished - Jan 1 1980

Fingerprint

Keto Acids
Aldehydes
Ions
Oxidation
Deprotonation
Decarboxylation
Micelles
Carboxylic Acids
Substrates
4,6-dinitro-o-cresol

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Facile oxidation of aldehydes and α-keto acids as catalyzed by flavin and thiazolium ion. / Shinkai, Seiji; Yamashita, Takaharu; Kusano, Yumiko; Manabe, Osamu.

In: Tetrahedron Letters, Vol. 21, No. 26, 01.01.1980, p. 2543-2546.

Research output: Contribution to journalArticle

Shinkai, Seiji ; Yamashita, Takaharu ; Kusano, Yumiko ; Manabe, Osamu. / Facile oxidation of aldehydes and α-keto acids as catalyzed by flavin and thiazolium ion. In: Tetrahedron Letters. 1980 ; Vol. 21, No. 26. pp. 2543-2546.
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