Facile synthesis of 9,10,19,20-tetraalkylporphycenes

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

meso-Tetraalkylporphycenes were synthesized in a few steps using intramolecular oxidative coupling of the Z-isomer of 5,6-dialkyldipyrroethenes. The use of a hypervalent iodine(III) reagent, namely phenyliodine(III) bis(trifluoroacetate), is essential for performing these reactions.

Original languageEnglish
Pages (from-to)260-262
Number of pages3
JournalChemistry Letters
Volume46
Issue number2
DOIs
Publication statusPublished - Jan 1 2017

Fingerprint

Iodine
Isomers
phenyliodine(III) bis(trifluoroacetate)

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Facile synthesis of 9,10,19,20-tetraalkylporphycenes. / Ono, Toshikazu; Koga, Daiki; Hisaeda, Yoshio.

In: Chemistry Letters, Vol. 46, No. 2, 01.01.2017, p. 260-262.

Research output: Contribution to journalArticle

@article{052dfb395fca44f3bb9e6cae4d4e5d21,
title = "Facile synthesis of 9,10,19,20-tetraalkylporphycenes",
abstract = "meso-Tetraalkylporphycenes were synthesized in a few steps using intramolecular oxidative coupling of the Z-isomer of 5,6-dialkyldipyrroethenes. The use of a hypervalent iodine(III) reagent, namely phenyliodine(III) bis(trifluoroacetate), is essential for performing these reactions.",
author = "Toshikazu Ono and Daiki Koga and Yoshio Hisaeda",
year = "2017",
month = "1",
day = "1",
doi = "10.1246/cl.161019",
language = "English",
volume = "46",
pages = "260--262",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "The Chemical Society of Japan",
number = "2",

}

TY - JOUR

T1 - Facile synthesis of 9,10,19,20-tetraalkylporphycenes

AU - Ono, Toshikazu

AU - Koga, Daiki

AU - Hisaeda, Yoshio

PY - 2017/1/1

Y1 - 2017/1/1

N2 - meso-Tetraalkylporphycenes were synthesized in a few steps using intramolecular oxidative coupling of the Z-isomer of 5,6-dialkyldipyrroethenes. The use of a hypervalent iodine(III) reagent, namely phenyliodine(III) bis(trifluoroacetate), is essential for performing these reactions.

AB - meso-Tetraalkylporphycenes were synthesized in a few steps using intramolecular oxidative coupling of the Z-isomer of 5,6-dialkyldipyrroethenes. The use of a hypervalent iodine(III) reagent, namely phenyliodine(III) bis(trifluoroacetate), is essential for performing these reactions.

UR - http://www.scopus.com/inward/record.url?scp=85011622746&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85011622746&partnerID=8YFLogxK

U2 - 10.1246/cl.161019

DO - 10.1246/cl.161019

M3 - Article

AN - SCOPUS:85011622746

VL - 46

SP - 260

EP - 262

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 2

ER -