Facile synthesis of 9,10,19,20-tetraalkylporphycenes

Toshikazu Ono; Daiki Koga; Yoshio Hisaeda

doi:10.1246/cl.161019

Facile synthesis of 9,10,19,20-tetraalkylporphycenes

Toshikazu Ono, Daiki Koga, Yoshio Hisaeda

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

meso-Tetraalkylporphycenes were synthesized in a few steps using intramolecular oxidative coupling of the Z-isomer of 5,6-dialkyldipyrroethenes. The use of a hypervalent iodine(III) reagent, namely phenyliodine(III) bis(trifluoroacetate), is essential for performing these reactions.

Original language	English
Pages (from-to)	260-262
Number of pages	3
Journal	Chemistry Letters
Volume	46
Issue number	2
DOIs	https://doi.org/10.1246/cl.161019
Publication status	Published - Jan 1 2017

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.161019

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abstract = "meso-Tetraalkylporphycenes were synthesized in a few steps using intramolecular oxidative coupling of the Z-isomer of 5,6-dialkyldipyrroethenes. The use of a hypervalent iodine(III) reagent, namely phenyliodine(III) bis(trifluoroacetate), is essential for performing these reactions.",

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