Facilitated Photoreduction of Ruthenium Bis(4́-methylterpyridine) Pendant Myoglobin

Itaru Hamachi, Tomoaki Matsugi, Shigeaki Tanaka, Seiji Shinkai

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

A synthetic heme bearing ruthenium bis(terpyridine) through a covalent bond was successfully prepared. Ruthenium bis(terpyridine) pendant myoglobin, which was synthesized by a conventional cofactor reconstitution method, was efficiently activated through a photoinduced electron-transfer reaction from the ruthenium complex to the heme center. No reaction occurred in the corresponding intermolecular reaction system.

Original languageEnglish
Pages (from-to)1657-1661
Number of pages5
JournalBulletin of the Chemical Society of Japan
Volume69
Issue number6
DOIs
Publication statusPublished - Jan 1 1996

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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