Ferromagnetic spin coupling in the manganese trimer ion evidenced by photodissociation spectroscopy

Akira Terasaki, Tina M. Briere, Maria Kulawik, Shinichirou Minemoto, Kensuke Tono, Akira Matsushita, Tamotsu Kondow

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20 Citations (Scopus)

Abstract

Ferromagnetic spin coupling was revealed in Mn3+ by the measurements of the photodissociation cross section in the near-ir-uv region and through quantum-chemical analysis of the spectrum. Calculations based on the density-functional theory hybridized with the Hartree-Fock theory were used to reproduce the experimental spectrum and explain the electronic structure of the cluster ion.

Original languageEnglish
Pages (from-to)2180-2185
Number of pages6
JournalJournal of Chemical Physics
Volume118
Issue number5
DOIs
Publication statusPublished - Feb 1 2003
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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    Terasaki, A., Briere, T. M., Kulawik, M., Minemoto, S., Tono, K., Matsushita, A., & Kondow, T. (2003). Ferromagnetic spin coupling in the manganese trimer ion evidenced by photodissociation spectroscopy. Journal of Chemical Physics, 118(5), 2180-2185. https://doi.org/10.1063/1.1534106