Ferromagnetic spin interaction through the interheteromolecular hydrogen bond: A 1:1 crystalline complex of phenylboronic acid and phenyl nttronyl nitroxide

Takeyuki Akita; Yasuhiro Mazaki; Keiji Kobayashi

doi:10.1080/10587259608042174

Ferromagnetic spin interaction through the interheteromolecular hydrogen bond: A 1:1 crystalline complex of phenylboronic acid and phenyl nttronyl nitroxide

Takeyuki Akita, Yasuhiro Mazaki, Keiji Kobayashi

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A crystalline molecular complex derived from phenyl nitronyl nitroxide (1) and phenyl boronic acid (2) exhibits a ferromagnetic spin interaction (J= +0.65 K) below 30 K: An X-ray analysis revealed the crystal structure constituted of one-dimensional array of two component molecules linked alternately by the NO-HO-B hydrogen bonds. The NO-HO-B-OH - ON linkage was suggested to act as a path for ferromagnetic spin coupling. An unusual formation of nitrosonium salt (3) was found in the reaction of 1 and BF₃. Its molecular and crystal structures were determined.

Original language	English
Pages (from-to)	39-45
Number of pages	7
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	278-279
DOIs	https://doi.org/10.1080/10587259608042174
Publication status	Published - Jan 1 1996
Externally published	Yes

All Science Journal Classification (ASJC) codes

Condensed Matter Physics

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Akita, T., Mazaki, Y., & Kobayashi, K. (1996). Ferromagnetic spin interaction through the interheteromolecular hydrogen bond: A 1:1 crystalline complex of phenylboronic acid and phenyl nttronyl nitroxide. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 278-279, 39-45. https://doi.org/10.1080/10587259608042174

Ferromagnetic spin interaction through the interheteromolecular hydrogen bond : A 1:1 crystalline complex of phenylboronic acid and phenyl nttronyl nitroxide. / Akita, Takeyuki; Mazaki, Yasuhiro; Kobayashi, Keiji.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 278-279, 01.01.1996, p. 39-45.

Research output: Contribution to journal › Article › peer-review

Akita, T, Mazaki, Y & Kobayashi, K 1996, 'Ferromagnetic spin interaction through the interheteromolecular hydrogen bond: A 1:1 crystalline complex of phenylboronic acid and phenyl nttronyl nitroxide', Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, vol. 278-279, pp. 39-45. https://doi.org/10.1080/10587259608042174

Akita T, Mazaki Y, Kobayashi K. Ferromagnetic spin interaction through the interheteromolecular hydrogen bond: A 1:1 crystalline complex of phenylboronic acid and phenyl nttronyl nitroxide. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals. 1996 Jan 1;278-279:39-45. https://doi.org/10.1080/10587259608042174

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