Abstract
A crystalline molecular complex derived from phenyl nitronyl nitroxide (1) and phenyl boronic acid (2) exhibits a ferromagnetic spin interaction (J= +0.65 K) below 30 K: An X-ray analysis revealed the crystal structure constituted of one-dimensional array of two component molecules linked alternately by the NO-HO-B hydrogen bonds. The NO-HO-B-OH - ON linkage was suggested to act as a path for ferromagnetic spin coupling. An unusual formation of nitrosonium salt (3) was found in the reaction of 1 and BF3. Its molecular and crystal structures were determined.
| Original language | English |
|---|---|
| Pages (from-to) | 39-45 |
| Number of pages | 7 |
| Journal | Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals |
| Volume | 278-279 |
| Publication status | Published - Dec 1 1996 |
Fingerprint
All Science Journal Classification (ASJC) codes
- Condensed Matter Physics
Cite this
Ferromagnetic spin interaction through the interheteromolecular hydrogen bond : A 1:1 crystalline complex of phenylboronic acid and phenyl nttronyl nitroxide. / Akita, Takeyuki; Mazaki, Yasuhiro; Kobayashi, Keiji.
In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 278-279, 01.12.1996, p. 39-45.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Ferromagnetic spin interaction through the interheteromolecular hydrogen bond
T2 - A 1:1 crystalline complex of phenylboronic acid and phenyl nttronyl nitroxide
AU - Akita, Takeyuki
AU - Mazaki, Yasuhiro
AU - Kobayashi, Keiji
PY - 1996/12/1
Y1 - 1996/12/1
N2 - A crystalline molecular complex derived from phenyl nitronyl nitroxide (1) and phenyl boronic acid (2) exhibits a ferromagnetic spin interaction (J= +0.65 K) below 30 K: An X-ray analysis revealed the crystal structure constituted of one-dimensional array of two component molecules linked alternately by the NO-HO-B hydrogen bonds. The NO-HO-B-OH - ON linkage was suggested to act as a path for ferromagnetic spin coupling. An unusual formation of nitrosonium salt (3) was found in the reaction of 1 and BF3. Its molecular and crystal structures were determined.
AB - A crystalline molecular complex derived from phenyl nitronyl nitroxide (1) and phenyl boronic acid (2) exhibits a ferromagnetic spin interaction (J= +0.65 K) below 30 K: An X-ray analysis revealed the crystal structure constituted of one-dimensional array of two component molecules linked alternately by the NO-HO-B hydrogen bonds. The NO-HO-B-OH - ON linkage was suggested to act as a path for ferromagnetic spin coupling. An unusual formation of nitrosonium salt (3) was found in the reaction of 1 and BF3. Its molecular and crystal structures were determined.
UR - http://www.scopus.com/inward/record.url?scp=5244331766&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=5244331766&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:5244331766
VL - 278-279
SP - 39
EP - 45
JO - Molecular Crystals and Liquid Crystals
JF - Molecular Crystals and Liquid Crystals
SN - 1542-1406
ER -