Film device to visualize UV irradiation

Kiyomi Takato, Yuuki Kaburagi, Yoshimi Kurimura, Sumio Tokita, Takaaki Noguchi, Masao Kaneko

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A film device to visualize UV irradiation was successfully fabricated by an agarose solid film containing Fluoran dye, acid generator N -tosyloxyphthalimide and 2-propanol medium, and the mechanism and kinetics of this system were investigated. The reactions involving: (1) acid generation from N -tosyloxyphthalimide by UV irradiation, (2) acid generation from N -tosyloxyphthalimide by chemical amplitude reaction, (3) coloring reaction of Fluoran dye by acid were analyzed by changing the Fluoran dye concentration. The concentration of the colored Fluoran dye was determined by the absorbance at 520 nm appearing by UV irradiation. The kinetic constants of the three reactions were estimated by solving the differential equations by the formation of the colored Fluoran dye with changing the parameters based on a least square method. The result was in accordance with the experimental results to give reaction rate constants of the processes.

Original languageEnglish
Pages (from-to)271-276
Number of pages6
JournalJournal of Photochemistry and Photobiology A: Chemistry
Volume163
Issue number1-2
DOIs
Publication statusPublished - Apr 15 2004
Externally publishedYes

Fingerprint

Coloring Agents
Dyes
dyes
Irradiation
irradiation
acids
Acids
Kinetics
2-Propanol
kinetics
Propanol
Coloring
least squares method
Sepharose
Reaction rates
Rate constants
reaction kinetics
Differential equations
differential equations
generators

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Physics and Astronomy(all)

Cite this

Film device to visualize UV irradiation. / Takato, Kiyomi; Kaburagi, Yuuki; Kurimura, Yoshimi; Tokita, Sumio; Noguchi, Takaaki; Kaneko, Masao.

In: Journal of Photochemistry and Photobiology A: Chemistry, Vol. 163, No. 1-2, 15.04.2004, p. 271-276.

Research output: Contribution to journalArticle

Takato, K, Kaburagi, Y, Kurimura, Y, Tokita, S, Noguchi, T & Kaneko, M 2004, 'Film device to visualize UV irradiation', Journal of Photochemistry and Photobiology A: Chemistry, vol. 163, no. 1-2, pp. 271-276. https://doi.org/10.1016/j.jphotochem.2003.12.011
Takato, Kiyomi ; Kaburagi, Yuuki ; Kurimura, Yoshimi ; Tokita, Sumio ; Noguchi, Takaaki ; Kaneko, Masao. / Film device to visualize UV irradiation. In: Journal of Photochemistry and Photobiology A: Chemistry. 2004 ; Vol. 163, No. 1-2. pp. 271-276.
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