First detection of a silicic acid complex with a catechol derivative under natural conditions

Shuqin Bai, Yutaka Tsuji, Yoshihiro Okaue, Takushi Yokoyama

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The formation of silicic acid-tiron complexes was predicted based on the increase in the solubility of amorphous silica in aqueous tiron solution near neutral pH compared with aqueous sodium chloride solutions of the same pH. A 6-coordinated silicic acid-tiron complex was detected by 29Si NMR and the composition was determined to be 1:3 (Si:tiron) by ESI mass spec-troscopy.

Original languageEnglish
Pages (from-to)1168-1169
Number of pages2
JournalChemistry Letters
Volume37
Issue number11
DOIs
Publication statusPublished - Dec 1 2008

Fingerprint

1,2-Dihydroxybenzene-3,5-Disulfonic Acid Disodium Salt
Silicic Acid
Derivatives
Sodium Chloride
Silicon Dioxide
Solubility
Nuclear magnetic resonance
catechol
Chemical analysis

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

First detection of a silicic acid complex with a catechol derivative under natural conditions. / Bai, Shuqin; Tsuji, Yutaka; Okaue, Yoshihiro; Yokoyama, Takushi.

In: Chemistry Letters, Vol. 37, No. 11, 01.12.2008, p. 1168-1169.

Research output: Contribution to journalArticle

Bai, Shuqin ; Tsuji, Yutaka ; Okaue, Yoshihiro ; Yokoyama, Takushi. / First detection of a silicic acid complex with a catechol derivative under natural conditions. In: Chemistry Letters. 2008 ; Vol. 37, No. 11. pp. 1168-1169.
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