First example of a rigid (μ-oxo-di-μ-acetato)diiron(III) complex with 1,2-bis[2-di(2-pyridyl)methyl-6-pyridyl]ethane; its efficient catalysis for functionalization of alkanes

Masahito Kodera, Hisashi Shimakoshi, Koji Kano

Research output: Contribution to journalArticle

69 Citations (Scopus)

Abstract

The μ-oxo-di-μ-acetatodiiron(III) complex [Fe2(hexpy)(O)-(OCOMe)2][ClO4]2 {hexpy = 1,2-bis[2-di(2-pyridyl)-methyl-6-pyridyl]ethane} efficiently catalyses the oxygenation of cyclohexane, methylcyclohexane and adamantane in the presence of m-chloroperbenzoic acid.

Original languageEnglish
Pages (from-to)1737-1738
Number of pages2
JournalChemical Communications
Issue number15
DOIs
Publication statusPublished - Jan 1 1996
Externally publishedYes

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Adamantane
Alkanes
Ethane
Oxygenation
Cyclohexane
Paraffins
Catalysis
Acids
perchlorate
3-chloroperbenzoic acid
methylcyclohexane

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

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abstract = "The μ-oxo-di-μ-acetatodiiron(III) complex [Fe2(hexpy)(O)-(OCOMe)2][ClO4]2 {hexpy = 1,2-bis[2-di(2-pyridyl)-methyl-6-pyridyl]ethane} efficiently catalyses the oxygenation of cyclohexane, methylcyclohexane and adamantane in the presence of m-chloroperbenzoic acid.",
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AU - Kodera, Masahito

AU - Shimakoshi, Hisashi

AU - Kano, Koji

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N2 - The μ-oxo-di-μ-acetatodiiron(III) complex [Fe2(hexpy)(O)-(OCOMe)2][ClO4]2 {hexpy = 1,2-bis[2-di(2-pyridyl)-methyl-6-pyridyl]ethane} efficiently catalyses the oxygenation of cyclohexane, methylcyclohexane and adamantane in the presence of m-chloroperbenzoic acid.

AB - The μ-oxo-di-μ-acetatodiiron(III) complex [Fe2(hexpy)(O)-(OCOMe)2][ClO4]2 {hexpy = 1,2-bis[2-di(2-pyridyl)-methyl-6-pyridyl]ethane} efficiently catalyses the oxygenation of cyclohexane, methylcyclohexane and adamantane in the presence of m-chloroperbenzoic acid.

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