First synthesis of all-trans-polyprenol with 100 carbons

Yusuke Totsuka, Yoko Yasuno, Tetsuro Shinada

Research output: Contribution to journalArticle

Abstract

All-trans polyprenols consisting of one hundred carbons (C100) have been synthesized for the first time via the sulfone coupling of C45 and C55 fragments. The resulting coupling product with four benzenesulfonyl groups were subjected to desulfonylation reaction using Pd(dppp)Cl2/LiBHEt3 followed by removal of the benzyl group at the tail under Benkeser reduction conditions to furnish the title compound.

Original languageEnglish
Pages (from-to)491-494
Number of pages4
JournalChemistry Letters
Volume48
Issue number5
DOIs
Publication statusPublished - Jan 1 2019
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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