First synthesis of tetrapyrrolylporphyrin

Hiroyuki Furuta, Hiromitsu Maeda, Takahiro Furuta, Atsuhiro Osuka

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

(matrix presented) N-Alkyl-substituted meso-tetrapyrrolylporphyrin (TPyrP) and its derivatives were synthesized for the first time via an acid-catalyzed condensation between N-alkyl-2,4-diformylpyrrole and unsubstituted pyrrole and a subsequent deformylation reaction. X-ray structural analysis of formyl-substituted TPyrP shows the tilting of meso pyrrole rings ca. 60° to the porphyrin plane. Formyl groups of meso pyrrole rings were removed by treatment with trifluoroacetic acid (TFA) in pyrrole.

Original languageEnglish
Pages (from-to)187-189
Number of pages3
JournalOrganic Letters
Volume2
Issue number2
DOIs
Publication statusPublished - Jan 27 2000
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Fingerprint Dive into the research topics of 'First synthesis of tetrapyrrolylporphyrin'. Together they form a unique fingerprint.

  • Cite this