Five new anthocyanins, ternatins A3, B4, B3, B2, and D2, from Clitoria ternatea flowers

Norihiko Terahara; Masahiro Oda; Toshiro Matsui; Yutaka Osajima; Norio Saito; Kenjiro Toki; Toshio Honda

doi:10.1021/np960050a

Five new anthocyanins, ternatins A3, B4, B3, B2, and D2, from Clitoria ternatea flowers

Norihiko Terahara, Masahiro Oda, Toshiro Matsui, Yutaka Osajima, Norio Saito, Kenjiro Toki, Toshio Honda

Food Science and Biotechnology

Research output: Contribution to journal › Article › peer-review

90 Citations (Scopus)

Abstract

Five new ternatins 1-5 have been isolated from Clitoria ternatea flowers, and the structures have been determined by chemical and spectroscopic methods as delphinidin 3-malonylG having 3'-GCG-5'-GCG, 3'- GCG-5'-GC, 3'-GCGCG-5'-GC, 3'-GCGC-5'-GCG, and 3'-GCGC-5'-GC side chains, respectively, in which G is p-glucose and C is p-coumaric acid. Pigment 1 had symmetric 3',5'-side chains. Compounds 3 and 4 are structural isomers. These ternatins were shown to form an intramolecular stacking between the aglycon ring and the 3',5'-side chains in solution.

Original language	English
Pages (from-to)	139-144
Number of pages	6
Journal	Journal of Natural Products
Volume	59
Issue number	2
DOIs	https://doi.org/10.1021/np960050a
Publication status	Published - Feb 1 1996

All Science Journal Classification (ASJC) codes

Analytical Chemistry
Molecular Medicine
Pharmacology
Pharmaceutical Science
Drug Discovery
Complementary and alternative medicine
Organic Chemistry

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10.1021/np960050a

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abstract = "Five new ternatins 1-5 have been isolated from Clitoria ternatea flowers, and the structures have been determined by chemical and spectroscopic methods as delphinidin 3-malonylG having 3'-GCG-5'-GCG, 3'- GCG-5'-GC, 3'-GCGCG-5'-GC, 3'-GCGC-5'-GCG, and 3'-GCGC-5'-GC side chains, respectively, in which G is p-glucose and C is p-coumaric acid. Pigment 1 had symmetric 3',5'-side chains. Compounds 3 and 4 are structural isomers. These ternatins were shown to form an intramolecular stacking between the aglycon ring and the 3',5'-side chains in solution.",

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T1 - Five new anthocyanins, ternatins A3, B4, B3, B2, and D2, from Clitoria ternatea flowers

AU - Terahara, Norihiko

AU - Oda, Masahiro

AU - Matsui, Toshiro

AU - Osajima, Yutaka

AU - Saito, Norio

AU - Toki, Kenjiro

AU - Honda, Toshio

PY - 1996/2/1

Y1 - 1996/2/1

N2 - Five new ternatins 1-5 have been isolated from Clitoria ternatea flowers, and the structures have been determined by chemical and spectroscopic methods as delphinidin 3-malonylG having 3'-GCG-5'-GCG, 3'- GCG-5'-GC, 3'-GCGCG-5'-GC, 3'-GCGC-5'-GCG, and 3'-GCGC-5'-GC side chains, respectively, in which G is p-glucose and C is p-coumaric acid. Pigment 1 had symmetric 3',5'-side chains. Compounds 3 and 4 are structural isomers. These ternatins were shown to form an intramolecular stacking between the aglycon ring and the 3',5'-side chains in solution.

AB - Five new ternatins 1-5 have been isolated from Clitoria ternatea flowers, and the structures have been determined by chemical and spectroscopic methods as delphinidin 3-malonylG having 3'-GCG-5'-GCG, 3'- GCG-5'-GC, 3'-GCGCG-5'-GC, 3'-GCGC-5'-GCG, and 3'-GCGC-5'-GC side chains, respectively, in which G is p-glucose and C is p-coumaric acid. Pigment 1 had symmetric 3',5'-side chains. Compounds 3 and 4 are structural isomers. These ternatins were shown to form an intramolecular stacking between the aglycon ring and the 3',5'-side chains in solution.

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Five new anthocyanins, ternatins A3, B4, B3, B2, and D2, from Clitoria ternatea flowers

Abstract

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