Flexible coordination of hetero-scorpionate ligands composed of pyrrole/pyridines hybrid in rhenium(I) tricarbonyl complexes

Motoki Toganoh, Naoyuki Harada, Hiroyuki Furuta

    Research output: Contribution to journalArticlepeer-review

    4 Citations (Scopus)

    Abstract

    Rhenium(I) coordination of hetero-scorpionate ligands composed of pyrrole/pyridines hybrid with four coordination sites on a single carbon atom afforded a variety of rhenium(I) tricarbonyl complexes. X-ray analyses on the rhenium(I) complexes revealed the flexible coordination of such hetero-scorpionate ligands. Presence of an additional coordinative site adjacent to the tridentate ligands lead to a unique supramolecular complex, anion recognizing complex, and bis-metal complex.

    Original languageEnglish
    Pages (from-to)1153-1158
    Number of pages6
    JournalPolyhedron
    Volume52
    DOIs
    Publication statusPublished - Mar 22 2013

    All Science Journal Classification (ASJC) codes

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry
    • Materials Chemistry

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