Flexible coordination of hetero-scorpionate ligands composed of pyrrole/pyridines hybrid in rhenium(I) tricarbonyl complexes

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Abstract

Rhenium(I) coordination of hetero-scorpionate ligands composed of pyrrole/pyridines hybrid with four coordination sites on a single carbon atom afforded a variety of rhenium(I) tricarbonyl complexes. X-ray analyses on the rhenium(I) complexes revealed the flexible coordination of such hetero-scorpionate ligands. Presence of an additional coordinative site adjacent to the tridentate ligands lead to a unique supramolecular complex, anion recognizing complex, and bis-metal complex.

Original languageEnglish
Pages (from-to)1153-1158
Number of pages6
JournalPolyhedron
Volume52
DOIs
Publication statusPublished - Mar 22 2013

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry
  • Materials Chemistry
  • Physical and Theoretical Chemistry

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