Flow analysis of micro amounts of chromium(III) and (VI) in natural water by solid phase spectrophotometry using diphenylcarbazide

Shiro Matsuoka, Yoshika Tennichi, Ko Takehara, Kazuhisa Yoshimura

Research output: Contribution to journalArticle

48 Citations (Scopus)

Abstract

Specific determination of chromium(III) and chromium(VI) in natural water samples was performed without mutual separation. The chromium in sample solution was concentrated on cation-exchange resin packed in a flow-through cell as a reaction product of chromium(VI) with diphenylcarbazide. The absorbance increase caused by the accumulation of the complex on cation-exchange resin was continuously measured. By using peroxodisulfate as an oxidizing agent, the chromium(III) in sample solution was completely oxidized to chromium(VI). The chromium(III) concentration was calculated by the difference between the values of the total chromium and chromium(VI). The detection limit for chromium(VI) and total chromium was 70 pg and 120 pg, respectively. This method was applied to the specific determination of chromium in several natural water samples. The results of the total chromium obtained by the proposed method show moderate agreement with that obtained with ICP-MS. Unlike the previous results reported in chromium speciation studies, the predominant chromium species in natural water was chromium(VI).

Original languageEnglish
Pages (from-to)787-791
Number of pages5
JournalAnalyst
Volume124
Issue number5
DOIs
Publication statusPublished - Jan 1 1999

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Diphenylcarbazide
Spectrophotometry
Chromium
spectrophotometry
chromium
Water
water
Cation Exchange Resins
chromium hexavalent ion
analysis
resin
ion exchange
Ion exchange
Reaction products
Oxidants
Resins
Positive ions
Limit of Detection

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Biochemistry
  • Environmental Chemistry
  • Spectroscopy
  • Electrochemistry

Cite this

Flow analysis of micro amounts of chromium(III) and (VI) in natural water by solid phase spectrophotometry using diphenylcarbazide. / Matsuoka, Shiro; Tennichi, Yoshika; Takehara, Ko; Yoshimura, Kazuhisa.

In: Analyst, Vol. 124, No. 5, 01.01.1999, p. 787-791.

Research output: Contribution to journalArticle

Matsuoka, Shiro ; Tennichi, Yoshika ; Takehara, Ko ; Yoshimura, Kazuhisa. / Flow analysis of micro amounts of chromium(III) and (VI) in natural water by solid phase spectrophotometry using diphenylcarbazide. In: Analyst. 1999 ; Vol. 124, No. 5. pp. 787-791.
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