Flow injection determination of anionic polyelectrolytes using an anionic surfactant-selective plasticized poly(vinyl chloride) membrane electrode detector

Takashi Masadome, Toshihiko Imato, Satoshi Itoh, Yasukazu Asano

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A potentiometric flow injection method for the determination of anionic polyelectrolytes utilizing a flow-through type surfactant-selective electrode detector is described. The method is based on the detection of the concentration increase of anionic surfactant liberated from a reagent stream containing an ion associate between cationic polyelectrolyte, poly(diallyldimethylammonium chloride) and anionic surfactant, dodecylbenzenesulfonate, which is caused by the formation of a polyion complex between cationic and anionic polyelectrolytes. The response of the electrode detector as a peak-shaped signal was obtained for injected anionic polyelectrolyte samples. A linear relationship was found to exist between peak height and the logarithmic concentration of potassium poly (vinyl sulfate) (PVSK) with a slope of 30 mV decade-1 in a concentration range of 1.0 × 10-4 to 1.0 × 10-3 mol/L. Identical relationships were obtained for sodium alginate and carageenan (also anionic polyelectrolytes) as for PVSK but with a lower sensitivity. The detection limit for PVSK was 2.5 × 10-5 mol/L. The relative standard deviation for 5 injections of a 2.5 × 10-4 mol/L PVSK solution was 1.3% and the sampling rate was ca. 10 samples h-1.

Original languageEnglish
Pages (from-to)901-903
Number of pages3
JournalFresenius' Journal of Analytical Chemistry
Volume357
Issue number7
DOIs
Publication statusPublished - Jan 1 1997

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Vinyl Chloride
Anionic surfactants
Polyelectrolytes
Surface-Active Agents
Electrodes
Detectors
Membranes
Injections
Sulfates
Limit of Detection
Potassium
Ions
Sampling
polycations

All Science Journal Classification (ASJC) codes

  • Biochemistry

Cite this

Flow injection determination of anionic polyelectrolytes using an anionic surfactant-selective plasticized poly(vinyl chloride) membrane electrode detector. / Masadome, Takashi; Imato, Toshihiko; Itoh, Satoshi; Asano, Yasukazu.

In: Fresenius' Journal of Analytical Chemistry, Vol. 357, No. 7, 01.01.1997, p. 901-903.

Research output: Contribution to journalArticle

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