Fluoride complexation of element 104, rutherfordium (Rf), investigated by cation-exchange chromatography

Yasuo Ishii, Atsushi Toyoshima, Kazuaki Tsukada, Masato Asai, Hayato Toume, Ichiro Nishinaka, Yuichiro Nagame, Sunao Miyashita, Tomotaka Mori, Hideo Suganuma, Hiromitsu Haba, Masami Sakamaki, Shin Ichi Goto, Hisaaki Kudo, Kazuhiko Akiyama, Yasuji Oura, Hiromichi Nakahara, Yuki Tashiro, Atsushi Shinohara, Matthias SchädelWilly Brüchle, Valeria Pershina, Jens V. Kratz

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

We report on new and much more precise cation-exchange data of element 104, rutherfordium (Rf), in the fluoride ion concentration [F-] range of 5.29 × 10-5-1.04 × 10-3 M. The result based on one-atom-at-a-time chemistry clearly demonstrates that the distribution coefficients (Kd) decrease with increasing [F-], suggesting successive fluoride complexation of Rf. The complexation of Rf is briefly discussed in terms of fully relativistic density functional calculation theory.

Original languageEnglish
Pages (from-to)288-289
Number of pages2
JournalChemistry Letters
Volume37
Issue number3
DOIs
Publication statusPublished - Mar 5 2008

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Chromatography
Complexation
Fluorides
Cations
Electronic data interchange
Density functional theory
Ions
Atoms
Rutherfordium

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Fluoride complexation of element 104, rutherfordium (Rf), investigated by cation-exchange chromatography. / Ishii, Yasuo; Toyoshima, Atsushi; Tsukada, Kazuaki; Asai, Masato; Toume, Hayato; Nishinaka, Ichiro; Nagame, Yuichiro; Miyashita, Sunao; Mori, Tomotaka; Suganuma, Hideo; Haba, Hiromitsu; Sakamaki, Masami; Goto, Shin Ichi; Kudo, Hisaaki; Akiyama, Kazuhiko; Oura, Yasuji; Nakahara, Hiromichi; Tashiro, Yuki; Shinohara, Atsushi; Schädel, Matthias; Brüchle, Willy; Pershina, Valeria; Kratz, Jens V.

In: Chemistry Letters, Vol. 37, No. 3, 05.03.2008, p. 288-289.

Research output: Contribution to journalArticle

Ishii, Y, Toyoshima, A, Tsukada, K, Asai, M, Toume, H, Nishinaka, I, Nagame, Y, Miyashita, S, Mori, T, Suganuma, H, Haba, H, Sakamaki, M, Goto, SI, Kudo, H, Akiyama, K, Oura, Y, Nakahara, H, Tashiro, Y, Shinohara, A, Schädel, M, Brüchle, W, Pershina, V & Kratz, JV 2008, 'Fluoride complexation of element 104, rutherfordium (Rf), investigated by cation-exchange chromatography', Chemistry Letters, vol. 37, no. 3, pp. 288-289. https://doi.org/10.1246/cl.2008.288
Ishii, Yasuo ; Toyoshima, Atsushi ; Tsukada, Kazuaki ; Asai, Masato ; Toume, Hayato ; Nishinaka, Ichiro ; Nagame, Yuichiro ; Miyashita, Sunao ; Mori, Tomotaka ; Suganuma, Hideo ; Haba, Hiromitsu ; Sakamaki, Masami ; Goto, Shin Ichi ; Kudo, Hisaaki ; Akiyama, Kazuhiko ; Oura, Yasuji ; Nakahara, Hiromichi ; Tashiro, Yuki ; Shinohara, Atsushi ; Schädel, Matthias ; Brüchle, Willy ; Pershina, Valeria ; Kratz, Jens V. / Fluoride complexation of element 104, rutherfordium (Rf), investigated by cation-exchange chromatography. In: Chemistry Letters. 2008 ; Vol. 37, No. 3. pp. 288-289.
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