TY - JOUR
T1 - Fluorinated hybrid polymers by copolymerization of trialkylsilyl methacrylate with fluoroalkyl methacrylate
AU - Fujiwara, Hirotada
AU - Narita, Tadashi
AU - Hamana, Hiroshi
AU - Shimizu, Koichi
N1 - Copyright:
Copyright 2008 Elsevier B.V., All rights reserved.
PY - 2002
Y1 - 2002
N2 - The easiest way to obtain fluorinated hybrid polymers possessing silicone atoms might be vinay copolymerization of fluorinated vinyl monomers with vinyl monomers possessing silyl groups as substituents. To prepare fluorinated hybrid polymers bearing alkylsilyl groups, copolymerization of fluoroalkyl methacrylates with alkylsilyl methacrylates was investigated, and the surface character of the copolymers was examined by measurement of the contact angle with water and methanol. This paper reports the copolymerization reactivity of tributylsilyl methacrylate (NBSM) with 2,2,2-trifluoroethyl methacrylate (TFEM) or 1-trifluoromethyl-2,2,2-trifluoroethyl methacrylate (Hx-FIM) initiated with benzoyl peroxide (BPO) or lithium butyldiethylzincate (LiZnBuEt2).
AB - The easiest way to obtain fluorinated hybrid polymers possessing silicone atoms might be vinay copolymerization of fluorinated vinyl monomers with vinyl monomers possessing silyl groups as substituents. To prepare fluorinated hybrid polymers bearing alkylsilyl groups, copolymerization of fluoroalkyl methacrylates with alkylsilyl methacrylates was investigated, and the surface character of the copolymers was examined by measurement of the contact angle with water and methanol. This paper reports the copolymerization reactivity of tributylsilyl methacrylate (NBSM) with 2,2,2-trifluoroethyl methacrylate (TFEM) or 1-trifluoromethyl-2,2,2-trifluoroethyl methacrylate (Hx-FIM) initiated with benzoyl peroxide (BPO) or lithium butyldiethylzincate (LiZnBuEt2).
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U2 - 10.1295/polymj.34.714
DO - 10.1295/polymj.34.714
M3 - Article
AN - SCOPUS:0036907197
VL - 34
SP - 714
EP - 717
JO - Polymer Journal
JF - Polymer Journal
SN - 0032-3896
IS - 9
ER -