Formal nucleophilic boryl substitution of organic halides with Silylborane/Alkoxy base system

Eiji Yamamoto, Kiyotaka Izumi, Yuko Horita, Satoshi Ukigai, Hajime Ito

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Boryl substitution of organohalides with a silylborane and alkoxy bases is described. This reaction can be applied to various functionalized aryl halides. Alkyl and alkenyl halides, and even sterically congested aryl bromides also provided the corresponding borylated products in high yields. Mechanistic studies indicated that neither trace transition-metal impurities nor aryl radical species involved in this reaction.

Original languageEnglish
Pages (from-to)940-945
Number of pages6
JournalTopics in Catalysis
Volume57
Issue number10-13
DOIs
Publication statusPublished - Jun 2014
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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