Formation and sinterability of La1-XCaXCrO 3 powder by a complex polymerization method

Ho Sik Shin, Masato Uehara, Naoya Enomoto, Junichi Hojo

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Calcium-doped lanthanum chromite powders were prepared by a complex polymerization method and their sintering behavior was investigated. The mixture solution of La(NO3)3·6H2O, Ca(NO 3)2·4H2O, Cr(NO3) 3·9H2O, citric acid and ethylene glycol was heated at 200°C to form a polymerized gel. When the precursor was heat-treated at 300°C, a lanthanum chromite phase was detected by XRD. The XRD peak of lanthanum chromite became sharp by heat treatment at 800°C. La 0.8Ca0.2CrO3 powder exhibited the single phase of lanthanum chromite. However, CaCrO4 was detected besides lanthanum chromite in La0.7Ca0.3CrO3 powder. When carbon black powder was used as inert filler, the fine powder of submicrometre size was obtained. The fine powder of calcium-doped lanthanum chromite had a high sinterability. The relative density of a La0.8Ca 0.2CrO3 sintered body was ≧96% at 1700°C in an Ar atmosphere.

Original languageEnglish
Pages (from-to)45-48
Number of pages4
JournalJournal of Ceramic Processing Research
Volume4
Issue number1
Publication statusPublished - Dec 1 2003

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Lanthanum
Chromite
Powders
Polymerization
Calcium
Soot
Ethylene Glycol
Citric acid
Carbon black
Ethylene glycol
Citric Acid
Fillers
Sintering
Gels
Heat treatment

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites

Cite this

Formation and sinterability of La1-XCaXCrO 3 powder by a complex polymerization method. / Shin, Ho Sik; Uehara, Masato; Enomoto, Naoya; Hojo, Junichi.

In: Journal of Ceramic Processing Research, Vol. 4, No. 1, 01.12.2003, p. 45-48.

Research output: Contribution to journalArticle

Shin, Ho Sik ; Uehara, Masato ; Enomoto, Naoya ; Hojo, Junichi. / Formation and sinterability of La1-XCaXCrO 3 powder by a complex polymerization method. In: Journal of Ceramic Processing Research. 2003 ; Vol. 4, No. 1. pp. 45-48.
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