Formation and spectroscopic characterization of the carbon monoxide adduct of an alkanethiolate-coordinated heme

Mikiya Matsu-Ura, Fumito Tani, Yoshinori Naruta

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The CO adduct of a thiolate-coordinated heme was obtained by two different methods and characterized by UV-vis and resonance Raman spectroscopy. The v(Fe-CO) band was observed at 428 cm-1. The unusually low frequency indicates the extremely strong σ-donation from the thiolate axial ligand to the heme iron.

Original languageEnglish
Pages (from-to)814-815
Number of pages2
JournalChemistry Letters
Issue number7
DOIs
Publication statusPublished - Jan 1 2000

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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