Formation and spectroscopic characterization of the carbon monoxide adduct of an alkanethiolate-coordinated heme

Mikiya Matsu-Ura; Fumito Tani; Yoshinori Naruta

doi:10.1246/cl.2000.814

Formation and spectroscopic characterization of the carbon monoxide adduct of an alkanethiolate-coordinated heme

Mikiya Matsu-Ura, Fumito Tani, Yoshinori Naruta

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The CO adduct of a thiolate-coordinated heme was obtained by two different methods and characterized by UV-vis and resonance Raman spectroscopy. The v(Fe-CO) band was observed at 428 cm^-1. The unusually low frequency indicates the extremely strong σ-donation from the thiolate axial ligand to the heme iron.

Original language	English
Pages (from-to)	814-815
Number of pages	2
Journal	Chemistry Letters
Issue number	7
DOIs	https://doi.org/10.1246/cl.2000.814
Publication status	Published - 2000

All Science Journal Classification (ASJC) codes

Chemistry(all)

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title = "Formation and spectroscopic characterization of the carbon monoxide adduct of an alkanethiolate-coordinated heme",

abstract = "The CO adduct of a thiolate-coordinated heme was obtained by two different methods and characterized by UV-vis and resonance Raman spectroscopy. The v(Fe-CO) band was observed at 428 cm-1. The unusually low frequency indicates the extremely strong σ-donation from the thiolate axial ligand to the heme iron.",

author = "Mikiya Matsu-Ura and Fumito Tani and Yoshinori Naruta",

year = "2000",

doi = "10.1246/cl.2000.814",

language = "English",

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journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

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AU - Matsu-Ura, Mikiya

AU - Tani, Fumito

AU - Naruta, Yoshinori

PY - 2000

Y1 - 2000

N2 - The CO adduct of a thiolate-coordinated heme was obtained by two different methods and characterized by UV-vis and resonance Raman spectroscopy. The v(Fe-CO) band was observed at 428 cm-1. The unusually low frequency indicates the extremely strong σ-donation from the thiolate axial ligand to the heme iron.

AB - The CO adduct of a thiolate-coordinated heme was obtained by two different methods and characterized by UV-vis and resonance Raman spectroscopy. The v(Fe-CO) band was observed at 428 cm-1. The unusually low frequency indicates the extremely strong σ-donation from the thiolate axial ligand to the heme iron.

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U2 - 10.1246/cl.2000.814

DO - 10.1246/cl.2000.814

M3 - Article

AN - SCOPUS:0034339603

SN - 0366-7022

SP - 814

EP - 815

JO - Chemistry Letters

JF - Chemistry Letters

IS - 7

ER -

Formation and spectroscopic characterization of the carbon monoxide adduct of an alkanethiolate-coordinated heme

Abstract

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