Formation of carbon nanotubes through ethylene decomposition over supported Pt catalysts and silica-coated Pt catalysts

Sakae Takenaka, Toshiyuki Iguchi, Eishi Tanabe, Hideki Matsune, Masahiro Kishida

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Ethylene decomposition was performed over supported Pt catalysts to fabricate composites of Pt metal nanoparticles and carbon nanotubes (CNTs). All supported Pt catalysts (Pt/carbon black, Pt/CNT, Pt/MgO, Pt/Al2O3 and Pt/SiO2) showed catalytic activity for ethylene decomposition at 973 K to form CNTs. Pt metal particles were found at tips of CNTs. These results indicate that Pt metal particles have catalytic activity for growth of CNTs through hydrocarbon decomposition. A broad range (5-50 nm) of CNT diameters were formed from the use of supported Pt metal catalysts although Pt metal particles in the catalysts before ethylene decomposition were relatively uniform in size (2-5 nm). These results imply that Pt metal particles in the catalysts aggregated during ethylene decomposition at 973 K. Aggregation of Pt metal particles in catalysts during ethylene decomposition could be suppressed by covering catalysts with silica layers that were a few nanometers thick. Silica-coated Pt catalysts showed high activity for ethylene decomposition to form CNTs with uniform diameters (8-10 nm) despite the uniform coverage of Pt metal particles with silica layers.

Original languageEnglish
Pages (from-to)1251-1257
Number of pages7
JournalCarbon
Volume47
Issue number5
DOIs
Publication statusPublished - Apr 1 2009

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Carbon Nanotubes
Catalyst supports
Silicon Dioxide
Carbon nanotubes
Ethylene
Metals
Silica
Decomposition
Catalysts
Catalyst activity
Soot
Metal nanoparticles
Hydrocarbons
Carbon black
ethylene
Agglomeration
Composite materials

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)

Cite this

Formation of carbon nanotubes through ethylene decomposition over supported Pt catalysts and silica-coated Pt catalysts. / Takenaka, Sakae; Iguchi, Toshiyuki; Tanabe, Eishi; Matsune, Hideki; Kishida, Masahiro.

In: Carbon, Vol. 47, No. 5, 01.04.2009, p. 1251-1257.

Research output: Contribution to journalArticle

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AU - Kishida, Masahiro

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AB - Ethylene decomposition was performed over supported Pt catalysts to fabricate composites of Pt metal nanoparticles and carbon nanotubes (CNTs). All supported Pt catalysts (Pt/carbon black, Pt/CNT, Pt/MgO, Pt/Al2O3 and Pt/SiO2) showed catalytic activity for ethylene decomposition at 973 K to form CNTs. Pt metal particles were found at tips of CNTs. These results indicate that Pt metal particles have catalytic activity for growth of CNTs through hydrocarbon decomposition. A broad range (5-50 nm) of CNT diameters were formed from the use of supported Pt metal catalysts although Pt metal particles in the catalysts before ethylene decomposition were relatively uniform in size (2-5 nm). These results imply that Pt metal particles in the catalysts aggregated during ethylene decomposition at 973 K. Aggregation of Pt metal particles in catalysts during ethylene decomposition could be suppressed by covering catalysts with silica layers that were a few nanometers thick. Silica-coated Pt catalysts showed high activity for ethylene decomposition to form CNTs with uniform diameters (8-10 nm) despite the uniform coverage of Pt metal particles with silica layers.

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