Formation of gold clusters on La-Ni mixed oxides and its catalytic performance for isomerization of allylic alcohols to saturated aldehydes

Tamao Ishida, Jun Aimoto, Akiyuki Hamasaki, Hironori Ohashi, Tetsuo Honma, Takushi Yokoyama, Kohei Sakata, Mitsutaka Okumura, Makoto Tokunaga

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Au/NiO catalyzed the isomerization of allylic alcohols to afford saturated aldehydes. LaNi mixed oxide could stabilize Au(III) and afford gold clusters smaller than 1 nm by H2reduction. The resulting Au clusters on La-Ni-O exhibited superior catalytic performance to Au/NiO for the isomerization of internal allylic alcohol, 2-octen-1-ol to octanal.

Original languageEnglish
Pages (from-to)1368-1370
Number of pages3
JournalChemistry Letters
Volume43
Issue number8
DOIs
Publication statusPublished - Jan 1 2014

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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