Formation of hydroxyl-functionalized stilbenoid molecular sieves at the liquid/solid interface on top of a 1-decanol monolayer

Amandine Bellec, Claire Arrigoni, Ludovic Douillard, Céline Fiorini-Debuisschert, Fabrice Dominique Mathevet, David Kreher, André Jean Attias, Fabrice Charra

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Specific molecular tectons can be designed to form molecular sieves through self-assembly at the solid-liquid interface. After demonstrating a model tecton bearing apolar alkyl chains, we then focus on a modified structure involving asymmetric functionalization of some alkyl chains with polar hydroxyl groups in order to get chemical selectivity in the sieving. As the formation of supramolecular self-assembled networks strongly depends on molecule-molecule, molecule-substrate and molecule-solvent interactions, we compared the tectons' self-assembly on graphite for two types of solvent. We demonstrate the possibility to create hydroxylated stilbenoid molecular sieves by using 1-decanol as a solvent. Interestingly, with this solvent, the porous network is developed on top of a 1-decanol monolayer.

Original languageEnglish
Article number435604
JournalNanotechnology
Volume25
Issue number43
DOIs
Publication statusPublished - Oct 31 2014

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Molecular sieves
Hydroxyl Radical
Monolayers
Molecules
Liquids
Self assembly
Bearings (structural)
Graphite
n-decyl alcohol
Substrates

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering
  • Electrical and Electronic Engineering

Cite this

Bellec, A., Arrigoni, C., Douillard, L., Fiorini-Debuisschert, C., Mathevet, F. D., Kreher, D., ... Charra, F. (2014). Formation of hydroxyl-functionalized stilbenoid molecular sieves at the liquid/solid interface on top of a 1-decanol monolayer. Nanotechnology, 25(43), [435604]. https://doi.org/10.1088/0957-4484/25/43/435604

Formation of hydroxyl-functionalized stilbenoid molecular sieves at the liquid/solid interface on top of a 1-decanol monolayer. / Bellec, Amandine; Arrigoni, Claire; Douillard, Ludovic; Fiorini-Debuisschert, Céline; Mathevet, Fabrice Dominique; Kreher, David; Attias, André Jean; Charra, Fabrice.

In: Nanotechnology, Vol. 25, No. 43, 435604, 31.10.2014.

Research output: Contribution to journalArticle

Bellec, A, Arrigoni, C, Douillard, L, Fiorini-Debuisschert, C, Mathevet, FD, Kreher, D, Attias, AJ & Charra, F 2014, 'Formation of hydroxyl-functionalized stilbenoid molecular sieves at the liquid/solid interface on top of a 1-decanol monolayer', Nanotechnology, vol. 25, no. 43, 435604. https://doi.org/10.1088/0957-4484/25/43/435604
Bellec, Amandine ; Arrigoni, Claire ; Douillard, Ludovic ; Fiorini-Debuisschert, Céline ; Mathevet, Fabrice Dominique ; Kreher, David ; Attias, André Jean ; Charra, Fabrice. / Formation of hydroxyl-functionalized stilbenoid molecular sieves at the liquid/solid interface on top of a 1-decanol monolayer. In: Nanotechnology. 2014 ; Vol. 25, No. 43.
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