Formation of nanoporous fibers by the self-assembly of a pyromellitic diimide-based macrocycle

Takeshi Nakagaki, Aya Harano, Yoko Fuchigami, Eishi Tanaka, Satoru Kidoaki, Tatsuya Okuda, Tetsuo Iwanaga, Kenta Goto, Teruo Shinmyozu

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Spaghetti sensor: A pyromellitic diimide based macrocycle selectively gelates N,N-dimethylaniline to form a nanofibril structure. Removal of N,N-dimethylaniline forms channel type empty cavities constructed from stacked molecules of the macrocycle in the nanofiber. By taking advantage of host ability of 1, the nanofibers can serve as a chemosensor for the π-donating compounds.

Original languageEnglish
Pages (from-to)9676-9679
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number50
DOIs
Publication statusPublished - Dec 10 2010

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Nanofibers
Self assembly
Fibers
Molecules
Sensors
pyromellitic diimide
N,N-dimethylaniline

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Formation of nanoporous fibers by the self-assembly of a pyromellitic diimide-based macrocycle. / Nakagaki, Takeshi; Harano, Aya; Fuchigami, Yoko; Tanaka, Eishi; Kidoaki, Satoru; Okuda, Tatsuya; Iwanaga, Tetsuo; Goto, Kenta; Shinmyozu, Teruo.

In: Angewandte Chemie - International Edition, Vol. 49, No. 50, 10.12.2010, p. 9676-9679.

Research output: Contribution to journalArticle

Nakagaki, Takeshi ; Harano, Aya ; Fuchigami, Yoko ; Tanaka, Eishi ; Kidoaki, Satoru ; Okuda, Tatsuya ; Iwanaga, Tetsuo ; Goto, Kenta ; Shinmyozu, Teruo. / Formation of nanoporous fibers by the self-assembly of a pyromellitic diimide-based macrocycle. In: Angewandte Chemie - International Edition. 2010 ; Vol. 49, No. 50. pp. 9676-9679.
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