Formation of supramolecular hetero-triads by controlling the hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction

Wataru Suzuki, Hiroaki Kotani, Tomoya Ishizuka, Yoshihito Shiota, Kazunari Yoshizawa, Takahiko Kojima

Research output: Contribution to journal › Article

3 Citations (Scopus)

Abstract

The thermodynamic stability of diprotonated saddle-distorted dodecaphenylporphyrin (H4DPP2+(X-)2) was controlled by the hydrogen-bonding strength of conjugate bases (X-) of strong acids (HX) or acids (R+-COOH) having positively charged moieties. The thermodynamic control of H4DPP2+(X-)2 made it possible to achieve selective formation of supramolecular hetero-triads, H4DPP2+(X-)(Cl-).

Original languageEnglish
Pages (from-to)6359-6362
Number of pages4
JournalChemical Communications
Volume53
Issue number47
DOIs
Publication statusPublished - Jan 1 2017

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Porphyrins
Coulomb interactions
Hydrogen bonds
Acids
Thermodynamic stability
Thermodynamics

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Formation of supramolecular hetero-triads by controlling the hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction. / Suzuki, Wataru; Kotani, Hiroaki; Ishizuka, Tomoya; Shiota, Yoshihito; Yoshizawa, Kazunari; Kojima, Takahiko.

In: Chemical Communications, Vol. 53, No. 47, 01.01.2017, p. 6359-6362.

Research output: Contribution to journal › Article

Suzuki, W, Kotani, H, Ishizuka, T, Shiota, Y, Yoshizawa, K & Kojima, T 2017, 'Formation of supramolecular hetero-triads by controlling the hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction', Chemical Communications, vol. 53, no. 47, pp. 6359-6362. https://doi.org/10.1039/c7cc03635c
Suzuki W, Kotani H, Ishizuka T, Shiota Y, Yoshizawa K, Kojima T. Formation of supramolecular hetero-triads by controlling the hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction. Chemical Communications. 2017 Jan 1;53(47):6359-6362. https://doi.org/10.1039/c7cc03635c
Suzuki, Wataru ; Kotani, Hiroaki ; Ishizuka, Tomoya ; Shiota, Yoshihito ; Yoshizawa, Kazunari ; Kojima, Takahiko. / Formation of supramolecular hetero-triads by controlling the hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction. In: Chemical Communications. 2017 ; Vol. 53, No. 47. pp. 6359-6362.
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