Abstract
The thermodynamic stability of diprotonated saddle-distorted dodecaphenylporphyrin (H4DPP2+(X-)2) was controlled by the hydrogen-bonding strength of conjugate bases (X-) of strong acids (HX) or acids (R+-COOH) having positively charged moieties. The thermodynamic control of H4DPP2+(X-)2 made it possible to achieve selective formation of supramolecular hetero-triads, H4DPP2+(X-)(Cl-).
| Original language | English |
|---|---|
| Pages (from-to) | 6359-6362 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 53 |
| Issue number | 47 |
| DOIs | |
| Publication status | Published - 2017 |
All Science Journal Classification (ASJC) codes
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
Fingerprint Dive into the research topics of 'Formation of supramolecular hetero-triads by controlling the hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction'. Together they form a unique fingerprint.
Cite this
Suzuki, W., Kotani, H., Ishizuka, T., Shiota, Y., Yoshizawa, K., & Kojima, T. (2017). Formation of supramolecular hetero-triads by controlling the hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction. Chemical Communications, 53(47), 6359-6362. https://doi.org/10.1039/c7cc03635c