Formation of supramolecular hetero-triads by controlling the hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction

Wataru Suzuki, Hiroaki Kotani, Tomoya Ishizuka, Yoshihito Shiota, Kazunari Yoshizawa, Takahiko Kojima

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The thermodynamic stability of diprotonated saddle-distorted dodecaphenylporphyrin (H4DPP2+(X-)2) was controlled by the hydrogen-bonding strength of conjugate bases (X-) of strong acids (HX) or acids (R+-COOH) having positively charged moieties. The thermodynamic control of H4DPP2+(X-)2 made it possible to achieve selective formation of supramolecular hetero-triads, H4DPP2+(X-)(Cl-).

Original languageEnglish
Pages (from-to)6359-6362
Number of pages4
JournalChemical Communications
Volume53
Issue number47
DOIs
Publication statusPublished - Jan 1 2017

Fingerprint

Porphyrins
Coulomb interactions
Hydrogen bonds
Acids
Thermodynamic stability
Thermodynamics

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Formation of supramolecular hetero-triads by controlling the hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction. / Suzuki, Wataru; Kotani, Hiroaki; Ishizuka, Tomoya; Shiota, Yoshihito; Yoshizawa, Kazunari; Kojima, Takahiko.

In: Chemical Communications, Vol. 53, No. 47, 01.01.2017, p. 6359-6362.

Research output: Contribution to journalArticle

@article{959b847c6d964ea2bb46ee695871a6e5,
title = "Formation of supramolecular hetero-triads by controlling the hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction",
abstract = "The thermodynamic stability of diprotonated saddle-distorted dodecaphenylporphyrin (H4DPP2+(X-)2) was controlled by the hydrogen-bonding strength of conjugate bases (X-) of strong acids (HX) or acids (R+-COOH) having positively charged moieties. The thermodynamic control of H4DPP2+(X-)2 made it possible to achieve selective formation of supramolecular hetero-triads, H4DPP2+(X-)(Cl-).",
author = "Wataru Suzuki and Hiroaki Kotani and Tomoya Ishizuka and Yoshihito Shiota and Kazunari Yoshizawa and Takahiko Kojima",
year = "2017",
month = "1",
day = "1",
doi = "10.1039/c7cc03635c",
language = "English",
volume = "53",
pages = "6359--6362",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "47",

}

TY - JOUR

T1 - Formation of supramolecular hetero-triads by controlling the hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction

AU - Suzuki, Wataru

AU - Kotani, Hiroaki

AU - Ishizuka, Tomoya

AU - Shiota, Yoshihito

AU - Yoshizawa, Kazunari

AU - Kojima, Takahiko

PY - 2017/1/1

Y1 - 2017/1/1

N2 - The thermodynamic stability of diprotonated saddle-distorted dodecaphenylporphyrin (H4DPP2+(X-)2) was controlled by the hydrogen-bonding strength of conjugate bases (X-) of strong acids (HX) or acids (R+-COOH) having positively charged moieties. The thermodynamic control of H4DPP2+(X-)2 made it possible to achieve selective formation of supramolecular hetero-triads, H4DPP2+(X-)(Cl-).

AB - The thermodynamic stability of diprotonated saddle-distorted dodecaphenylporphyrin (H4DPP2+(X-)2) was controlled by the hydrogen-bonding strength of conjugate bases (X-) of strong acids (HX) or acids (R+-COOH) having positively charged moieties. The thermodynamic control of H4DPP2+(X-)2 made it possible to achieve selective formation of supramolecular hetero-triads, H4DPP2+(X-)(Cl-).

UR - http://www.scopus.com/inward/record.url?scp=85021698093&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85021698093&partnerID=8YFLogxK

U2 - 10.1039/c7cc03635c

DO - 10.1039/c7cc03635c

M3 - Article

VL - 53

SP - 6359

EP - 6362

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 47

ER -