Four-electron reduction of a new ruthenium dicarbonyl complex having two NAD model ligands through decarboxylation in water

Takashi Fukushima, Debashis Ghosh, Katsuaki Kobayashi, Hideki Ohtsu, Susumu Kitagawa, Koji Tanaka

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

Three Ru-CO complexes, [Ru(pbn)2(CO)2]2+, [Ru(pbn)2(CO)(COOH)]+, [Ru(pbn)2(CO)(COO)]0 [pbn = 2-(pyridin-2-yl)benzo[b]-1,5-naphthyridine], exist as equilibrium mixtures in aqueous solutions. Thermal decarboxylation of [Ru(pbn)2(CO)(COOH)]+ and/or [Ru(pbn)2(CO)(COO)]0 induces a two-electron reduction of pbn to form [Ru(pbn)(pbnHH)(CO)(OH2)]2+ [pbnHH = 2-(pyridin-2-yl)-5,10-dihydrobenzo[b]-1,5-naphthyridine] in H2O.

Original languageEnglish
Pages (from-to)11613-11616
Number of pages4
JournalInorganic chemistry
Volume55
Issue number22
DOIs
Publication statusPublished - Nov 21 2016
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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