Frontispiece: Heterometallic FeIII/K Coordination Polymer with a Wide Thermal Hysteretic Spin Transition at Room Temperature

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Abstract

The FeIII anionic complex exhibiting cooperative spin transition with a wide thermal hysteresis near room temperature, K[Fe(5-Brthsa)2] (5-Brthsa-H2=5-bromosalicylaldehyde thiosemicarbazone), is reported. The hysteresis shows a one-step transition in heating mode and a two-step transition in cooling mode. X-ray structure analysis shows the coexistence of hydrogen bond and cation-π interactions, along with metal coordination bonds, to give 2D coordination polymer structure.

Original languageEnglish
Number of pages1
JournalChemistry - A European Journal
Volume22
Issue number2
DOIs
Publication statusPublished - Jan 1 2016

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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