Fullerene (C60)-Ag+ interactions which induce a solution color change

Atsushi Ikeda; Chie Fukuhara; Seiji Shinkai

doi:10.1016/0040-4039(96)01581-X

Fullerene (C₆₀)-Ag⁺ interactions which induce a solution color change

Atsushi Ikeda, Chie Fukuhara, Seiji Shinkai

Institute for Advanced Study

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

It was found that C₆₀ bearing an NCH₂CH₂(OCH₂CH₂)₂OMe side chain changes its absorption spectrum (and consequently, its visual color) upon addition of AgCF₃SO₃. The spectroscopic studies established that Ag⁺ directly interacts with C = C double bonds on the C₆₀ surface. This system serves as a novel methodology to change spectroscopic and redox properties of C₆₀ by added metal cations.

Original language	English
Pages (from-to)	7091-7094
Number of pages	4
Journal	Tetrahedron Letters
Volume	37
Issue number	39
DOIs	https://doi.org/10.1016/0040-4039(96)01581-X
Publication status	Published - Sep 23 1996

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/0040-4039(96)01581-X

Fingerprint Dive into the research topics of 'Fullerene (C<sub>60</sub>)-Ag<sup>+</sup> interactions which induce a solution color change'. Together they form a unique fingerprint.

Cite this

@article{e7e01897060948d3ab788f68d522a8f4,

title = "Fullerene (C60)-Ag+ interactions which induce a solution color change",

abstract = "It was found that C60 bearing an NCH2CH2(OCH2CH2)2OMe side chain changes its absorption spectrum (and consequently, its visual color) upon addition of AgCF3SO3. The spectroscopic studies established that Ag+ directly interacts with C = C double bonds on the C60 surface. This system serves as a novel methodology to change spectroscopic and redox properties of C60 by added metal cations.",

author = "Atsushi Ikeda and Chie Fukuhara and Seiji Shinkai",

year = "1996",

month = sep,

day = "23",

doi = "10.1016/0040-4039(96)01581-X",

language = "English",

volume = "37",

pages = "7091--7094",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "39",

}

TY - JOUR

T1 - Fullerene (C60)-Ag+ interactions which induce a solution color change

AU - Ikeda, Atsushi

AU - Fukuhara, Chie

AU - Shinkai, Seiji

PY - 1996/9/23

Y1 - 1996/9/23

N2 - It was found that C60 bearing an NCH2CH2(OCH2CH2)2OMe side chain changes its absorption spectrum (and consequently, its visual color) upon addition of AgCF3SO3. The spectroscopic studies established that Ag+ directly interacts with C = C double bonds on the C60 surface. This system serves as a novel methodology to change spectroscopic and redox properties of C60 by added metal cations.

AB - It was found that C60 bearing an NCH2CH2(OCH2CH2)2OMe side chain changes its absorption spectrum (and consequently, its visual color) upon addition of AgCF3SO3. The spectroscopic studies established that Ag+ directly interacts with C = C double bonds on the C60 surface. This system serves as a novel methodology to change spectroscopic and redox properties of C60 by added metal cations.

UR - http://www.scopus.com/inward/record.url?scp=0030599262&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0030599262&partnerID=8YFLogxK

U2 - 10.1016/0040-4039(96)01581-X

DO - 10.1016/0040-4039(96)01581-X

M3 - Article

AN - SCOPUS:0030599262

VL - 37

SP - 7091

EP - 7094

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 39

ER -