Fullerene (C60)-Ag+ interactions which induce a solution color change

Atsushi Ikeda; Chie Fukuhara; Seiji Shinkai

doi:10.1016/0040-4039(96)01581-X

Fullerene (C₆₀)-Ag⁺ interactions which induce a solution color change

Atsushi Ikeda, Chie Fukuhara, Seiji Shinkai

Institute for Advanced Study

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

It was found that C₆₀ bearing an NCH₂CH₂(OCH₂CH₂)₂OMe side chain changes its absorption spectrum (and consequently, its visual color) upon addition of AgCF₃SO₃. The spectroscopic studies established that Ag⁺ directly interacts with C = C double bonds on the C₆₀ surface. This system serves as a novel methodology to change spectroscopic and redox properties of C₆₀ by added metal cations.

Original language	English
Pages (from-to)	7091-7094
Number of pages	4
Journal	Tetrahedron Letters
Volume	37
Issue number	39
DOIs	https://doi.org/10.1016/0040-4039(96)01581-X
Publication status	Published - Sep 23 1996

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Fullerene (C60)-Ag+ interactions which induce a solution color change",

abstract = "It was found that C60 bearing an NCH2CH2(OCH2CH2)2OMe side chain changes its absorption spectrum (and consequently, its visual color) upon addition of AgCF3SO3. The spectroscopic studies established that Ag+ directly interacts with C = C double bonds on the C60 surface. This system serves as a novel methodology to change spectroscopic and redox properties of C60 by added metal cations.",

author = "Atsushi Ikeda and Chie Fukuhara and Seiji Shinkai",

note = "Funding Information: This work is financially supported, in part, by a Grant-in-Aid from the Ministry of Education, Culture and Science.",

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AU - Ikeda, Atsushi

AU - Fukuhara, Chie

AU - Shinkai, Seiji

N1 - Funding Information: This work is financially supported, in part, by a Grant-in-Aid from the Ministry of Education, Culture and Science.

PY - 1996/9/23

Y1 - 1996/9/23

N2 - It was found that C60 bearing an NCH2CH2(OCH2CH2)2OMe side chain changes its absorption spectrum (and consequently, its visual color) upon addition of AgCF3SO3. The spectroscopic studies established that Ag+ directly interacts with C = C double bonds on the C60 surface. This system serves as a novel methodology to change spectroscopic and redox properties of C60 by added metal cations.

AB - It was found that C60 bearing an NCH2CH2(OCH2CH2)2OMe side chain changes its absorption spectrum (and consequently, its visual color) upon addition of AgCF3SO3. The spectroscopic studies established that Ag+ directly interacts with C = C double bonds on the C60 surface. This system serves as a novel methodology to change spectroscopic and redox properties of C60 by added metal cations.

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SN - 0040-4039

IS - 39

ER -

Fullerene (C₆₀)-Ag⁺ interactions which induce a solution color change

Abstract

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