Gallium(III)corrole-BODIPY hybrid: Novel photophysical properties and first observation of B-F⋯F interactions

Biju Basumatary, R. V. Ramana Reddy, Subhrajyoti Bhandary, Jeyaraman Sankar

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

Anchoring a BODIPY onto Ga(iii)corrole via a meso-β linkage facilitated PeT in polar solvents, which quenched the fluorescence, and is further confirmed by electrochemical studies. The triad exhibits unprecedented crystal emission, which is not known for a corrole derivative, due to unique packing. Compound 4 hosts the first example of a novel B-F⋯F interaction as well.

Original languageEnglish
Pages (from-to)20817-20821
Number of pages5
JournalDalton Transactions
Volume44
Issue number48
DOIs
Publication statusPublished - 2015
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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