Generation of silylethynolates via C-Si bond cleavage of disilylketenes induced by t-BuOK

Masato Ito, Eiji Shirakawa, Hidemasa Takaya

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Disilylketenes undergo selective mono-desilylation upon treatment of t-BuOK in the presence of HMPA. The resulting silylethynolates are convertible to other disilylketenes in good yields. The intermediary silylethynolate was analyzed by NMR and IR spectroscopy.

Original languageEnglish
Pages (from-to)1329-1331
Number of pages3
JournalSynlett
Issue number8
DOIs
Publication statusPublished - Jan 1 2002
Externally publishedYes

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Nuclear magnetic resonance spectroscopy
Infrared spectroscopy

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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Generation of silylethynolates via C-Si bond cleavage of disilylketenes induced by t-BuOK. / Ito, Masato; Shirakawa, Eiji; Takaya, Hidemasa.

In: Synlett, No. 8, 01.01.2002, p. 1329-1331.

Research output: Contribution to journalArticle

Ito, Masato ; Shirakawa, Eiji ; Takaya, Hidemasa. / Generation of silylethynolates via C-Si bond cleavage of disilylketenes induced by t-BuOK. In: Synlett. 2002 ; No. 8. pp. 1329-1331.
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