Generation of silylethynolates via C-Si bond cleavage of disilylketenes induced by t-BuOK

Masato Ito; Eiji Shirakawa; Hidemasa Takaya

doi:10.1055/s-2002-32975

Generation of silylethynolates via C-Si bond cleavage of disilylketenes induced by t-BuOK

Masato Ito, Eiji Shirakawa, Hidemasa Takaya

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Disilylketenes undergo selective mono-desilylation upon treatment of t-BuOK in the presence of HMPA. The resulting silylethynolates are convertible to other disilylketenes in good yields. The intermediary silylethynolate was analyzed by NMR and IR spectroscopy.

Original language	English
Pages (from-to)	1329-1331
Number of pages	3
Journal	Synlett
Issue number	8
DOIs	https://doi.org/10.1055/s-2002-32975
Publication status	Published - Jan 1 2002
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry

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title = "Generation of silylethynolates via C-Si bond cleavage of disilylketenes induced by t-BuOK",

abstract = "Disilylketenes undergo selective mono-desilylation upon treatment of t-BuOK in the presence of HMPA. The resulting silylethynolates are convertible to other disilylketenes in good yields. The intermediary silylethynolate was analyzed by NMR and IR spectroscopy.",

author = "Masato Ito and Eiji Shirakawa and Hidemasa Takaya",

year = "2002",

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doi = "10.1055/s-2002-32975",

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T1 - Generation of silylethynolates via C-Si bond cleavage of disilylketenes induced by t-BuOK

AU - Ito, Masato

AU - Shirakawa, Eiji

AU - Takaya, Hidemasa

PY - 2002/1/1

Y1 - 2002/1/1

N2 - Disilylketenes undergo selective mono-desilylation upon treatment of t-BuOK in the presence of HMPA. The resulting silylethynolates are convertible to other disilylketenes in good yields. The intermediary silylethynolate was analyzed by NMR and IR spectroscopy.

AB - Disilylketenes undergo selective mono-desilylation upon treatment of t-BuOK in the presence of HMPA. The resulting silylethynolates are convertible to other disilylketenes in good yields. The intermediary silylethynolate was analyzed by NMR and IR spectroscopy.

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DO - 10.1055/s-2002-32975

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ER -

Generation of silylethynolates via C-Si bond cleavage of disilylketenes induced by t-BuOK

Abstract

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