Graded oxide glasses in binary systems (Si-Ti, Si-V, and Si-Zr) prepared by the sol -gel and centrifugal process

T. Mashimo, M. Ichikawa, E. Omurzak, M. Nishihara, H. Ihara

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Graded oxide glasses in binary oxide systems (Si-Ti, Si-V, and Si-Zr) had been prepared by means of a sol -gel method combined with centrifugal processing. In the Si-Ti and Si-V oxide systems, the graded oxide glasses, whose composition continuously changed with dimension in molecular scale, were prepared. The FT-IR analysis showed that infrared absorption peaks of Si-O-Si stretching and bending shifted, and Ti-O-Si or V-O-Si bands appeared with increasing the concentration of Ti or V, respectively. In the Si-Zr oxide system, the graded oxide glass in which the ZrO 2 nanocrystals appeared in the high gravity region was prepared.

Original languageEnglish
Pages (from-to)2339-2343
Number of pages5
JournalChemistry of Materials
Volume21
Issue number12
DOIs
Publication statusPublished - Jun 23 2009
Externally publishedYes

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Oxides
Sol-gels
Glass
Infrared absorption
Nanocrystals
Sol-gel process
Stretching
Gravitation
Processing
Chemical analysis

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

Cite this

Graded oxide glasses in binary systems (Si-Ti, Si-V, and Si-Zr) prepared by the sol -gel and centrifugal process. / Mashimo, T.; Ichikawa, M.; Omurzak, E.; Nishihara, M.; Ihara, H.

In: Chemistry of Materials, Vol. 21, No. 12, 23.06.2009, p. 2339-2343.

Research output: Contribution to journalArticle

Mashimo, T. ; Ichikawa, M. ; Omurzak, E. ; Nishihara, M. ; Ihara, H. / Graded oxide glasses in binary systems (Si-Ti, Si-V, and Si-Zr) prepared by the sol -gel and centrifugal process. In: Chemistry of Materials. 2009 ; Vol. 21, No. 12. pp. 2339-2343.
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AU - Ihara, H.

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