Gram-scale synthesis of nickel(II) norcorrole: The smallest antiaromatic porphyrinoid

Tomohiro Ito, Yosuke Hayashi, Soji Shimizu, Ji Young Shin, Nagao Kobayashi, Hiroshi Shinokubo

Research output: Contribution to journalArticle

99 Citations (Scopus)

Abstract

Small is beautiful: A ring-contracted sister of porphyrin, norcorrole, has been synthesized efficiently as a stable molecule by a nickel-templated strategy. The norcorrole complex is stable but exhibits a distinct antiaromatic character according to the Hückel rule. Oxidation of the norcorrole complex provides an aromatic oxacorrole complex.

Original languageEnglish
Pages (from-to)8542-8545
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number34
DOIs
Publication statusPublished - Aug 20 2012
Externally publishedYes

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Porphyrins
Nickel
Oxidation
Molecules

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Gram-scale synthesis of nickel(II) norcorrole : The smallest antiaromatic porphyrinoid. / Ito, Tomohiro; Hayashi, Yosuke; Shimizu, Soji; Shin, Ji Young; Kobayashi, Nagao; Shinokubo, Hiroshi.

In: Angewandte Chemie - International Edition, Vol. 51, No. 34, 20.08.2012, p. 8542-8545.

Research output: Contribution to journalArticle

Ito, Tomohiro ; Hayashi, Yosuke ; Shimizu, Soji ; Shin, Ji Young ; Kobayashi, Nagao ; Shinokubo, Hiroshi. / Gram-scale synthesis of nickel(II) norcorrole : The smallest antiaromatic porphyrinoid. In: Angewandte Chemie - International Edition. 2012 ; Vol. 51, No. 34. pp. 8542-8545.
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