Group 10 metal complexes of mesoaryl-substituted [26]hexaphyrins with a metal-carbon bond

Shigeki Mori, Soji Shimizu, Ryuichiro Taniguchi, Atsuhiro Osuka

Research output: Contribution to journalArticlepeer-review

67 Citations (Scopus)

Abstract

Nickel(II), palladium(II), and platinum(II) complexes of meso-arylsubstituted [26]hexaphyrin have been prepared and structurally characterized. In mono-metalated complexes, the metal ion is commonly bound with three pyrrolic nitrogen atoms and one pyrrolic β-carbon, whereas a bis-Pd(II) complex exhibits a unique structure involving a Pd-C α bond. These results reveal novel coordination abilities of the hexaphyrin that lead to a metal-carbon bond at either pyrrolic C β or Cα position.

Original languageEnglish
Pages (from-to)4127-4129
Number of pages3
JournalInorganic Chemistry
Volume44
Issue number12
DOIs
Publication statusPublished - Jun 13 2005
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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