Group 12 metal complexes of [26]hexaphyrin(1.1.1.1.1.1)

Shigeki Mori, Soji Shimizu, Ji Young Shin, Atsuhiro Osuka

Research output: Contribution to journalArticlepeer-review

38 Citations (Scopus)

Abstract

Metalation of meso-hexakis(pentafluorophenyl)-substituted [26]-hexaphyrin(1.1.1.1.1.1) (1) has been explored with group 12 metal ions Zn(II), Cd(II), and Hg(II). Zn(II) and Cd(II) ions afforded dinuclear gable-shaped complexes 2 and 3 in good yields, while Hg(II) ion provided bis-Hg(II) and mono-Hg(II) planar complexes (4 and 5) via C-H bond cleavage.

Original languageEnglish
Pages (from-to)4374-4376
Number of pages3
JournalInorganic chemistry
Volume46
Issue number11
DOIs
Publication statusPublished - May 28 2007
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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