Group 12 metal complexes of [26]hexaphyrin(1.1.1.1.1.1)

Shigeki Mori, Soji Shimizu, Ji Young Shin, Atsuhiro Osuka

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

Metalation of meso-hexakis(pentafluorophenyl)-substituted [26]-hexaphyrin(1.1.1.1.1.1) (1) has been explored with group 12 metal ions Zn(II), Cd(II), and Hg(II). Zn(II) and Cd(II) ions afforded dinuclear gable-shaped complexes 2 and 3 in good yields, while Hg(II) ion provided bis-Hg(II) and mono-Hg(II) planar complexes (4 and 5) via C-H bond cleavage.

Original languageEnglish
Pages (from-to)4374-4376
Number of pages3
JournalInorganic Chemistry
Volume46
Issue number11
DOIs
Publication statusPublished - May 28 2007
Externally publishedYes

Fingerprint

Coordination Complexes
Ions
metals
Metal ions
cleavage
metal ions
ions

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Group 12 metal complexes of [26]hexaphyrin(1.1.1.1.1.1). / Mori, Shigeki; Shimizu, Soji; Shin, Ji Young; Osuka, Atsuhiro.

In: Inorganic Chemistry, Vol. 46, No. 11, 28.05.2007, p. 4374-4376.

Research output: Contribution to journalArticle

Mori, Shigeki ; Shimizu, Soji ; Shin, Ji Young ; Osuka, Atsuhiro. / Group 12 metal complexes of [26]hexaphyrin(1.1.1.1.1.1). In: Inorganic Chemistry. 2007 ; Vol. 46, No. 11. pp. 4374-4376.
@article{27225da494cb4070a1a9d651fca16e6b,
title = "Group 12 metal complexes of [26]hexaphyrin(1.1.1.1.1.1)",
abstract = "Metalation of meso-hexakis(pentafluorophenyl)-substituted [26]-hexaphyrin(1.1.1.1.1.1) (1) has been explored with group 12 metal ions Zn(II), Cd(II), and Hg(II). Zn(II) and Cd(II) ions afforded dinuclear gable-shaped complexes 2 and 3 in good yields, while Hg(II) ion provided bis-Hg(II) and mono-Hg(II) planar complexes (4 and 5) via C-H bond cleavage.",
author = "Shigeki Mori and Soji Shimizu and Shin, {Ji Young} and Atsuhiro Osuka",
year = "2007",
month = "5",
day = "28",
doi = "10.1021/ic7004216",
language = "English",
volume = "46",
pages = "4374--4376",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "11",

}

TY - JOUR

T1 - Group 12 metal complexes of [26]hexaphyrin(1.1.1.1.1.1)

AU - Mori, Shigeki

AU - Shimizu, Soji

AU - Shin, Ji Young

AU - Osuka, Atsuhiro

PY - 2007/5/28

Y1 - 2007/5/28

N2 - Metalation of meso-hexakis(pentafluorophenyl)-substituted [26]-hexaphyrin(1.1.1.1.1.1) (1) has been explored with group 12 metal ions Zn(II), Cd(II), and Hg(II). Zn(II) and Cd(II) ions afforded dinuclear gable-shaped complexes 2 and 3 in good yields, while Hg(II) ion provided bis-Hg(II) and mono-Hg(II) planar complexes (4 and 5) via C-H bond cleavage.

AB - Metalation of meso-hexakis(pentafluorophenyl)-substituted [26]-hexaphyrin(1.1.1.1.1.1) (1) has been explored with group 12 metal ions Zn(II), Cd(II), and Hg(II). Zn(II) and Cd(II) ions afforded dinuclear gable-shaped complexes 2 and 3 in good yields, while Hg(II) ion provided bis-Hg(II) and mono-Hg(II) planar complexes (4 and 5) via C-H bond cleavage.

UR - http://www.scopus.com/inward/record.url?scp=34250696545&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34250696545&partnerID=8YFLogxK

U2 - 10.1021/ic7004216

DO - 10.1021/ic7004216

M3 - Article

VL - 46

SP - 4374

EP - 4376

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 11

ER -