Guest-Dependent Spin-Transition Behavior of Porous Coordination Polymers

Ryo Ohtani, Shinya Hayami

Research output: Contribution to journalReview article

24 Citations (Scopus)

Abstract

The host–guest composites of Hofmann-type iron(II) spin-transition (ST) porous coordination polymers incorporating guest molecules show guest-dependent ST behavior in accordance with the respective guest species, which may be a gas, solvent, halogen, or organic molecule. The guest also works as a chemical stimulant to switch the spin state of the host between high and low spin at room temperature. In this review, we discuss guest properties including size, shape, flexibility, chemical properties, and pore loading content, which impact the spin states of the host framework and the ST behavior exhibited by the host–guest composites.

Original languageEnglish
Pages (from-to)2236-2248
Number of pages13
JournalChemistry - A European Journal
Volume23
Issue number10
DOIs
Publication statusPublished - Feb 16 2017

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Polymers
Molecules
Halogens
Composite materials
Chemical properties
Iron
Gases
Switches
Temperature

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

Cite this

Guest-Dependent Spin-Transition Behavior of Porous Coordination Polymers. / Ohtani, Ryo; Hayami, Shinya.

In: Chemistry - A European Journal, Vol. 23, No. 10, 16.02.2017, p. 2236-2248.

Research output: Contribution to journalReview article

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