Heat and mass transfer in a concentric-annular-tube bed packed with ZrV1.9Fe0.1 particles

Satoshi Fukada, S. Morimitsu, N. Shimoozaki

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Pressure-composition isotherms of the ZrV1.9Fe 0.1-hydrogen system were determined by a constant volume method and were correlated to an empirical van't Hoff equation. The enthalpy change of hydrogen absorption was correlated to a function of the hydrogen-to-alloy atomic molar ratio. The entropy change was independent of it. Heat and mass transfer process in a concentric-annular-tube bed packed with the ZrV 1.9Fe0.1 particles was studied experimentally and numerically as a basic study of hydrogen storage at elevated temperature. A one-dimensional concentric-annular-tube bed was charged with hydrogen. The experimental profiles of hydrogen partial pressure and temperature were compared with numerical simulation calculated by the pressure-composition isotherm, a hydrogenating rate equation and two balance equations of hydrogen and heat. Another simplified analysis using three dimensionless lump parameters succeeded in estimating temperature profiles in the hydrogen-absorbing-alloy bed more easily. The simulation was able to make it better to understand contributions of experimental parameters such as the flow rate, surrounding temperature and other physical properties.

Original languageEnglish
Pages (from-to)305-312
Number of pages8
JournalJournal of Alloys and Compounds
Volume375
Issue number1-2
DOIs
Publication statusPublished - Jul 28 2004

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Packed beds
Hydrogen
Mass transfer
Heat transfer
Isotherms
Temperature
Hydrogen storage
Chemical analysis
Partial pressure
Enthalpy
Entropy
Physical properties
Flow rate
Computer simulation

All Science Journal Classification (ASJC) codes

  • Metals and Alloys

Cite this

Heat and mass transfer in a concentric-annular-tube bed packed with ZrV1.9Fe0.1 particles. / Fukada, Satoshi; Morimitsu, S.; Shimoozaki, N.

In: Journal of Alloys and Compounds, Vol. 375, No. 1-2, 28.07.2004, p. 305-312.

Research output: Contribution to journalArticle

Fukada, Satoshi ; Morimitsu, S. ; Shimoozaki, N. / Heat and mass transfer in a concentric-annular-tube bed packed with ZrV1.9Fe0.1 particles. In: Journal of Alloys and Compounds. 2004 ; Vol. 375, No. 1-2. pp. 305-312.
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